Iron(III) nitrilotriacetate and iron(III) iminodiacetate, their X-ray crystallographic structures and chemical properties

Marc Anton Walters; Vadim Vapnyar; Adam Bolour; Chris Incarvito; Arnold L. Rheingold

doi:10.1016/S0277-5387(03)00020-2

Iron(III) nitrilotriacetate and iron(III) iminodiacetate, their X-ray crystallographic structures and chemical properties

Marc Anton Walters, Vadim Vapnyar, Adam Bolour, Chris Incarvito, Arnold L. Rheingold

Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

Mononuclear iron(III) nitrilotriacetato dichloride, [Fe(nta)Cl₂]^2-, and iron(III) bis-iminodiacetato, [Fe(ida)₂]^-, complexes were formed in py, from which they were isolated and characterized by X-ray crystallography. The iron-nta complex is the structurally simplest of the reported solid state iron-nta complexes, and is catalytic for the air oxidation of hydrogen sulfide to sulfur.

Original language	English (US)
Pages (from-to)	941-946
Number of pages	6
Journal	Polyhedron
Volume	22
Issue number	7
DOIs	https://doi.org/10.1016/S0277-5387(03)00020-2
State	Published - Apr 1 2003

Keywords

Crystal structures
Hydrogen sulfide
Iminodiacetate
Iron
Nitrilotriacetate

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Inorganic Chemistry
Materials Chemistry

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10.1016/S0277-5387(03)00020-2

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title = "Iron(III) nitrilotriacetate and iron(III) iminodiacetate, their X-ray crystallographic structures and chemical properties",

abstract = "Mononuclear iron(III) nitrilotriacetato dichloride, [Fe(nta)Cl2]2-, and iron(III) bis-iminodiacetato, [Fe(ida)2]-, complexes were formed in py, from which they were isolated and characterized by X-ray crystallography. The iron-nta complex is the structurally simplest of the reported solid state iron-nta complexes, and is catalytic for the air oxidation of hydrogen sulfide to sulfur.",

keywords = "Crystal structures, Hydrogen sulfide, Iminodiacetate, Iron, Nitrilotriacetate",

author = "Walters, {Marc Anton} and Vadim Vapnyar and Adam Bolour and Chris Incarvito and Rheingold, {Arnold L.}",

year = "2003",

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doi = "10.1016/S0277-5387(03)00020-2",

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T1 - Iron(III) nitrilotriacetate and iron(III) iminodiacetate, their X-ray crystallographic structures and chemical properties

AU - Walters, Marc Anton

AU - Vapnyar, Vadim

AU - Bolour, Adam

AU - Incarvito, Chris

AU - Rheingold, Arnold L.

PY - 2003/4/1

Y1 - 2003/4/1

N2 - Mononuclear iron(III) nitrilotriacetato dichloride, [Fe(nta)Cl2]2-, and iron(III) bis-iminodiacetato, [Fe(ida)2]-, complexes were formed in py, from which they were isolated and characterized by X-ray crystallography. The iron-nta complex is the structurally simplest of the reported solid state iron-nta complexes, and is catalytic for the air oxidation of hydrogen sulfide to sulfur.

AB - Mononuclear iron(III) nitrilotriacetato dichloride, [Fe(nta)Cl2]2-, and iron(III) bis-iminodiacetato, [Fe(ida)2]-, complexes were formed in py, from which they were isolated and characterized by X-ray crystallography. The iron-nta complex is the structurally simplest of the reported solid state iron-nta complexes, and is catalytic for the air oxidation of hydrogen sulfide to sulfur.

KW - Crystal structures

KW - Hydrogen sulfide

KW - Iminodiacetate

KW - Iron

KW - Nitrilotriacetate

UR - http://www.scopus.com/inward/record.url?scp=0037379498&partnerID=8YFLogxK

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DO - 10.1016/S0277-5387(03)00020-2

M3 - Article

AN - SCOPUS:0037379498

SN - 0277-5387

VL - 22

SP - 941

EP - 946

JO - Polyhedron

JF - Polyhedron

IS - 7

ER -

Iron(III) nitrilotriacetate and iron(III) iminodiacetate, their X-ray crystallographic structures and chemical properties

Abstract

Keywords

ASJC Scopus subject areas

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