Iron(III) nitrilotriacetate and iron(III) iminodiacetate, their X-ray crystallographic structures and chemical properties

Marc Anton Walters, Vadim Vapnyar, Adam Bolour, Chris Incarvito, Arnold L. Rheingold

Research output: Contribution to journalArticle

Abstract

Mononuclear iron(III) nitrilotriacetato dichloride, [Fe(nta)Cl2]2-, and iron(III) bis-iminodiacetato, [Fe(ida)2]-, complexes were formed in py, from which they were isolated and characterized by X-ray crystallography. The iron-nta complex is the structurally simplest of the reported solid state iron-nta complexes, and is catalytic for the air oxidation of hydrogen sulfide to sulfur.

Original languageEnglish (US)
Pages (from-to)941-946
Number of pages6
JournalPolyhedron
Volume22
Issue number7
DOIs
StatePublished - Apr 1 2003

Keywords

  • Crystal structures
  • Hydrogen sulfide
  • Iminodiacetate
  • Iron
  • Nitrilotriacetate

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Inorganic Chemistry
  • Materials Chemistry

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