TY - JOUR

T1 - Irreducible spherical tensor analysis of quadrupolar nuclei

AU - Chandra Shekar, S.

AU - Rong, Peng

AU - Jerschow, Alexej

N1 - Funding Information:
We acknowledge funding from the US National Science Foundation, Grant # 0554400. We would like to thank Dr. Chin Lin of the department’s shared instrumentation facility for assistance with the NMR instrument.

PY - 2008/10/23

Y1 - 2008/10/23

N2 - Irreducible spherical tensor analysis can be used to select both the order and the rank of tensor componenets of the density matrix. This procedure was demonstrated for a collection of dipolar-coupled spin I = frac(1, 2) nuclei. In this work we adapt this approach for quadrupolar nuclei. We demonstrate this technique using the I = frac(7, 2) NMR spectra from 133Cs in an anisotropic phase. The separation of all possible ranks is shown. In this form the experiment can be useful in the analysis of both coherent and dissipative dynamics of quadrupolar nuclei.

AB - Irreducible spherical tensor analysis can be used to select both the order and the rank of tensor componenets of the density matrix. This procedure was demonstrated for a collection of dipolar-coupled spin I = frac(1, 2) nuclei. In this work we adapt this approach for quadrupolar nuclei. We demonstrate this technique using the I = frac(7, 2) NMR spectra from 133Cs in an anisotropic phase. The separation of all possible ranks is shown. In this form the experiment can be useful in the analysis of both coherent and dissipative dynamics of quadrupolar nuclei.

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U2 - 10.1016/j.cplett.2008.08.072

DO - 10.1016/j.cplett.2008.08.072

M3 - Article

AN - SCOPUS:53549102197

VL - 464

SP - 235

EP - 239

JO - Chemical Physics Letters

JF - Chemical Physics Letters

SN - 0009-2614

IS - 4-6

ER -