Irreducible spherical tensor analysis of quadrupolar nuclei

S. Chandra Shekar; Peng Rong; Alexej Jerschow

doi:10.1016/j.cplett.2008.08.072

Irreducible spherical tensor analysis of quadrupolar nuclei

S. Chandra Shekar, Peng Rong, Alexej Jerschow

Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

Irreducible spherical tensor analysis can be used to select both the order and the rank of tensor componenets of the density matrix. This procedure was demonstrated for a collection of dipolar-coupled spin I = frac(1, 2) nuclei. In this work we adapt this approach for quadrupolar nuclei. We demonstrate this technique using the I = frac(7, 2) NMR spectra from ¹³³Cs in an anisotropic phase. The separation of all possible ranks is shown. In this form the experiment can be useful in the analysis of both coherent and dissipative dynamics of quadrupolar nuclei.

Original language	English (US)
Pages (from-to)	235-239
Number of pages	5
Journal	Chemical Physics Letters
Volume	464
Issue number	4-6
DOIs	https://doi.org/10.1016/j.cplett.2008.08.072
State	Published - Oct 23 2008

ASJC Scopus subject areas

General Physics and Astronomy
Physical and Theoretical Chemistry

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10.1016/j.cplett.2008.08.072

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title = "Irreducible spherical tensor analysis of quadrupolar nuclei",

abstract = "Irreducible spherical tensor analysis can be used to select both the order and the rank of tensor componenets of the density matrix. This procedure was demonstrated for a collection of dipolar-coupled spin I = frac(1, 2) nuclei. In this work we adapt this approach for quadrupolar nuclei. We demonstrate this technique using the I = frac(7, 2) NMR spectra from 133Cs in an anisotropic phase. The separation of all possible ranks is shown. In this form the experiment can be useful in the analysis of both coherent and dissipative dynamics of quadrupolar nuclei.",

author = "{Chandra Shekar}, S. and Peng Rong and Alexej Jerschow",

note = "Funding Information: We acknowledge funding from the US National Science Foundation, Grant # 0554400. We would like to thank Dr. Chin Lin of the department{\textquoteright}s shared instrumentation facility for assistance with the NMR instrument. ",

year = "2008",

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AU - Chandra Shekar, S.

AU - Rong, Peng

AU - Jerschow, Alexej

N1 - Funding Information: We acknowledge funding from the US National Science Foundation, Grant # 0554400. We would like to thank Dr. Chin Lin of the department’s shared instrumentation facility for assistance with the NMR instrument.

PY - 2008/10/23

Y1 - 2008/10/23

N2 - Irreducible spherical tensor analysis can be used to select both the order and the rank of tensor componenets of the density matrix. This procedure was demonstrated for a collection of dipolar-coupled spin I = frac(1, 2) nuclei. In this work we adapt this approach for quadrupolar nuclei. We demonstrate this technique using the I = frac(7, 2) NMR spectra from 133Cs in an anisotropic phase. The separation of all possible ranks is shown. In this form the experiment can be useful in the analysis of both coherent and dissipative dynamics of quadrupolar nuclei.

AB - Irreducible spherical tensor analysis can be used to select both the order and the rank of tensor componenets of the density matrix. This procedure was demonstrated for a collection of dipolar-coupled spin I = frac(1, 2) nuclei. In this work we adapt this approach for quadrupolar nuclei. We demonstrate this technique using the I = frac(7, 2) NMR spectra from 133Cs in an anisotropic phase. The separation of all possible ranks is shown. In this form the experiment can be useful in the analysis of both coherent and dissipative dynamics of quadrupolar nuclei.

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JO - Chemical Physics Letters

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Irreducible spherical tensor analysis of quadrupolar nuclei

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