Is a Bent Crystal Still a Single Crystal?

Patrick Commins, Durga Prasad Karothu, Panče Naumov

Research output: Contribution to journalArticle

Abstract

The mention of the word “crystal” invokes images of minerals, gems, and rocks, all of which are inevitably solid, hard, and durable entities with well-defined smooth faces and straight edges. With the discovery in the first half of the 20th century that many molecular crystals are soft and can be deformed in a similar way as rubber or plastic, this perception is changing, and both the concept and formal definition of what a crystal is may require reinterpretation. The seemingly naïve question posed in the title of this Minireview does not have a simple answer. Here, we discuss how the effects of the elastic and plastic deformation of molecular crystals on the diffraction signature give primary evidence of their degree of crystallinity. In most cases, the definition of a crystal holds for both elastically and plastically deformed crystals and, unless there is significant or complete physical separation of the crystal during the deformation, they can safely be considered (deformed) single crystals with a high concentration of defects.

Original languageEnglish (US)
Pages (from-to)10052-10060
Number of pages9
JournalAngewandte Chemie - International Edition
Volume58
Issue number30
DOIs
StatePublished - Jul 22 2019

Keywords

  • X-ray diffraction
  • adaptive crystals
  • mechanical properties
  • solid-state structures

ASJC Scopus subject areas

  • Catalysis
  • Chemistry(all)

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