Kinematic effects in rotationally inelastic A + BC collisions

K. Raghavan, N. Sathyamurthy, B. A. Garetz

Research output: Contribution to journalArticlepeer-review

Abstract

Three-dimensional quasiclassical trajectory results obtained using an ab initio potential energy surface for rigid rotor HFLi collisions exhibit an interesting kinematic effect: with increase in mass of the projectile atom the amount of rotational energy transferred decreases in contrast to the reverse trend known in homonuclear diatom-atom collisions. The differing kinematics effects are explained on the basis of differing effective anisotropies that become evident in plots of potential energy contours in mass-weighted coordinates (R, δ) proposed recently by Loesch. We also work out the conditions for multiple collisions using different ellipse models.

Original languageEnglish (US)
Pages (from-to)187-199
Number of pages13
JournalChemical Physics
Volume113
Issue number2
DOIs
StatePublished - Apr 15 1987

ASJC Scopus subject areas

  • Physics and Astronomy(all)
  • Physical and Theoretical Chemistry

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