Lamellae-nanotube isomerism in hydrogen-bonded host frameworks

Matthew J. Horner, K. Travis Holman, Michael D. Ward

Research output: Contribution to journalArticle

Abstract

Inclusion compounds based on a flexible hydrogen-bonded sheet of guanidinium ions and sulfonate moieties display lamellar and tubular architectures, depending on the guest and the organic substituent attached to the sulfonate. The observed single-crystal architectures resemble lamellar and hexagonal microstructures (see picture) in block copolymers and surfactant assemblies.

Original languageEnglish (US)
Pages (from-to)4045-4048
Number of pages4
JournalAngewandte Chemie - International Edition
Volume40
Issue number21
DOIs
StatePublished - Nov 5 2001

Keywords

  • Clathrates
  • Crystal engineering
  • Inclusion compounds
  • Nanotubes
  • Self-assembly
  • Template synthesis

ASJC Scopus subject areas

  • Catalysis
  • Chemistry(all)

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