Local thermodynamics of inhomogeneous fluids at equilibrium

Jerome K. Percus, Liudmila A. Pozhar, Keith E. Gubbins

Research output: Contribution to journalArticlepeer-review

Abstract

Extensive thermodynamic parameters of inhomogeneous fluids in thermal equilibrium are expressed as integrals of corresponding locally defined quantities. In particular, the distinction between the grand canonical potential and the integrated mechanical pressure is discussed in terms of scale invariance, and a similar analysis is made of the Helmholtz free energy.

Original languageEnglish (US)
Pages (from-to)261-265
Number of pages5
JournalPhysical Review E
Volume51
Issue number1
DOIs
StatePublished - 1995

ASJC Scopus subject areas

  • Statistical and Nonlinear Physics
  • Statistics and Probability
  • Condensed Matter Physics

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