MACROMOLECULAR STEREOCHEMISTRY: HIGH FIELD **1**3C NMR AND PHOTON CORRELATION SPECTRA OF POLY( alpha -METHYL BENZYL ISONITRILES).

Mark M. Green; Richard A. Gross; Karl Zero; Charles Crosby; Frederic C. Schilling

MACROMOLECULAR STEREOCHEMISTRY: HIGH FIELD 13C NMR AND PHOTON CORRELATION SPECTRA OF POLY( alpha -METHYL BENZYL ISONITRILES).

Mark M. Green, Richard A. Gross, Karl Zero, Charles Crosby, Frederic C. Schilling

Chemical and Biomolecular Engineering

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution

Abstract

The authors examine the conformation of poly( alpha -methyl benzyl isonitrile). Experimental results indicate that the chemical shifts are consistent with the structure and the broadening of the resonance indicates some restriction in local chain motion. There is also clearly evident significant chemical shift dispersion as is exhibited in the expansion. This requires that the nuclei in both the backbone and in the pendant groups find access to a variety of environments, a state which is inconsistent with the strong bias toward regular conformations suggested by the literature.

Original language	English (US)
Title of host publication	American Chemical Society, Polymer Preprints, Division of Polymer Chemistry
Editors	Bill M. Culbertson, Judith S. Riffle, Frank D. Blum, Harry W. Gibson
Publisher	Div of Polymer Chemistry Inc
Pages	339-340
Number of pages	2
Volume	28
Edition	2
State	Published - Aug 1987
Event	Polym Prepr -Pap Presented at the New Orleans, LA Meet - New Orleans, LA, USA Duration: Aug 30 1987 → Sep 4 1987

Other

Other	Polym Prepr -Pap Presented at the New Orleans, LA Meet
City	New Orleans, LA, USA
Period	8/30/87 → 9/4/87

ASJC Scopus subject areas

Polymers and Plastics

Cite this

Green, M. M., Gross, R. A., Zero, K., Crosby, C., & Schilling, F. C. (1987). MACROMOLECULAR STEREOCHEMISTRY: HIGH FIELD **1**3C NMR AND PHOTON CORRELATION SPECTRA OF POLY( alpha -METHYL BENZYL ISONITRILES). In B. M. Culbertson, J. S. Riffle, F. D. Blum, & H. W. Gibson (Eds.), American Chemical Society, Polymer Preprints, Division of Polymer Chemistry (2 ed., Vol. 28, pp. 339-340). Div of Polymer Chemistry Inc.

MACROMOLECULAR STEREOCHEMISTRY: HIGH FIELD **1**3C NMR AND PHOTON CORRELATION SPECTRA OF POLY( alpha -METHYL BENZYL ISONITRILES). / Green, Mark M.; Gross, Richard A.; Zero, Karl et al.
American Chemical Society, Polymer Preprints, Division of Polymer Chemistry. ed. / Bill M. Culbertson; Judith S. Riffle; Frank D. Blum; Harry W. Gibson. Vol. 28 2. ed. Div of Polymer Chemistry Inc, 1987. p. 339-340.

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution

Green, MM, Gross, RA, Zero, K, Crosby, C & Schilling, FC 1987, MACROMOLECULAR STEREOCHEMISTRY: HIGH FIELD **1**3C NMR AND PHOTON CORRELATION SPECTRA OF POLY( alpha -METHYL BENZYL ISONITRILES). in BM Culbertson, JS Riffle, FD Blum & HW Gibson (eds), American Chemical Society, Polymer Preprints, Division of Polymer Chemistry. 2 edn, vol. 28, Div of Polymer Chemistry Inc, pp. 339-340, Polym Prepr -Pap Presented at the New Orleans, LA Meet, New Orleans, LA, USA, 8/30/87.

Green MM, Gross RA, Zero K, Crosby C, Schilling FC. MACROMOLECULAR STEREOCHEMISTRY: HIGH FIELD **1**3C NMR AND PHOTON CORRELATION SPECTRA OF POLY( alpha -METHYL BENZYL ISONITRILES). In Culbertson BM, Riffle JS, Blum FD, Gibson HW, editors, American Chemical Society, Polymer Preprints, Division of Polymer Chemistry. 2 ed. Vol. 28. Div of Polymer Chemistry Inc. 1987. p. 339-340

Green, Mark M. ; Gross, Richard A. ; Zero, Karl et al. / MACROMOLECULAR STEREOCHEMISTRY : HIGH FIELD **1**3C NMR AND PHOTON CORRELATION SPECTRA OF POLY( alpha -METHYL BENZYL ISONITRILES). American Chemical Society, Polymer Preprints, Division of Polymer Chemistry. editor / Bill M. Culbertson ; Judith S. Riffle ; Frank D. Blum ; Harry W. Gibson. Vol. 28 2. ed. Div of Polymer Chemistry Inc, 1987. pp. 339-340

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abstract = "The authors examine the conformation of poly( alpha -methyl benzyl isonitrile). Experimental results indicate that the chemical shifts are consistent with the structure and the broadening of the resonance indicates some restriction in local chain motion. There is also clearly evident significant chemical shift dispersion as is exhibited in the expansion. This requires that the nuclei in both the backbone and in the pendant groups find access to a variety of environments, a state which is inconsistent with the strong bias toward regular conformations suggested by the literature.",

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AB - The authors examine the conformation of poly( alpha -methyl benzyl isonitrile). Experimental results indicate that the chemical shifts are consistent with the structure and the broadening of the resonance indicates some restriction in local chain motion. There is also clearly evident significant chemical shift dispersion as is exhibited in the expansion. This requires that the nuclei in both the backbone and in the pendant groups find access to a variety of environments, a state which is inconsistent with the strong bias toward regular conformations suggested by the literature.

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MACROMOLECULAR STEREOCHEMISTRY: HIGH FIELD 13C NMR AND PHOTON CORRELATION SPECTRA OF POLY( alpha -METHYL BENZYL ISONITRILES).

Abstract

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ASJC Scopus subject areas

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