Abstract
Mapping of the diffusion equation in a channel of varying cross section onto the longitudinal coordinate is already a well studied procedure for a slowly changing radius. We examine here the mapping of diffusion in a channel with abrupt change of diameter. In two dimensions, our considerations are based on solution of the exactly solvable geometry with abruptly doubled width at x=0. We verify the surmise of Berezhkovskii [J. Chem. Phys. 131, 224110 (2009)]10.1063/1.3271998 that one-dimensional diffusion behaves as free in such channels everywhere except at the point of change, which looks like a local trap for the particles. Applying the method of "sewing" of solutions, we show that this picture is valid also for three-dimensional symmetric channels.
Original language | English (US) |
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Article number | 031143 |
Journal | Physical Review E - Statistical, Nonlinear, and Soft Matter Physics |
Volume | 82 |
Issue number | 3 |
DOIs | |
State | Published - Sep 30 2010 |
ASJC Scopus subject areas
- Statistical and Nonlinear Physics
- Statistics and Probability
- Condensed Matter Physics