Abstract
Polymer chains were investigated in the theta condition confined to a slit in a wide range of concentrations using mean-field Gaussian chain theory. The effective potential for the Gaussian chain was obtained using various existing lattice chain theories. Monomer density profile, partition coefficient and the chain dimension across the slit were calculated. It was shown that the density profile and the partition coefficient reflect the interaction between polymer chains.
Original language | English (US) |
---|---|
Pages (from-to) | 11362-11370 |
Number of pages | 9 |
Journal | Journal of Chemical Physics |
Volume | 115 |
Issue number | 24 |
DOIs | |
State | Published - Dec 22 2001 |
ASJC Scopus subject areas
- General Physics and Astronomy
- Physical and Theoretical Chemistry