Mechanistic Modeling of Epoxy-Amine Kinetics. 2. Comparison of Kinetics in Thermal and Microwave Fields

Jovan Mijovic; Arnon Fishbain; Jony Wijaya

doi:10.1021/ma00028a073

Mechanistic Modeling of Epoxy-Amine Kinetics. 2. Comparison of Kinetics in Thermal and Microwave Fields

Jovan Mijovic, Arnon Fishbain, Jony Wijaya

Chemical and Biomolecular Engineering

Research output: Contribution to journal › Article › peer-review

Abstract

An investigation was conducted to compare the rates and mechanisms of epoxy-amine reactions in thermal and microwave fields. A monofunctional model compound formulation and a multifunctional epoxy formulation were analyzed. Chromatographic, spectroscopic, and calorimetric techniques were utilized to generate data. Excellent agreement was observed between the proposed mechanistic model and experimental results. It was unequivocally found that the use of microwave energy in lieu of thermal energy had no effect on the reaction kinetics.

Original language	English (US)
Pages (from-to)	986-989
Number of pages	4
Journal	Macromolecules
Volume	25
Issue number	2
DOIs	https://doi.org/10.1021/ma00028a073
State	Published - Mar 1 1992

ASJC Scopus subject areas

Organic Chemistry
Polymers and Plastics
Inorganic Chemistry
Materials Chemistry

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abstract = "An investigation was conducted to compare the rates and mechanisms of epoxy-amine reactions in thermal and microwave fields. A monofunctional model compound formulation and a multifunctional epoxy formulation were analyzed. Chromatographic, spectroscopic, and calorimetric techniques were utilized to generate data. Excellent agreement was observed between the proposed mechanistic model and experimental results. It was unequivocally found that the use of microwave energy in lieu of thermal energy had no effect on the reaction kinetics.",

author = "Jovan Mijovic and Arnon Fishbain and Jony Wijaya",

year = "1992",

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AU - Fishbain, Arnon

AU - Wijaya, Jony

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Y1 - 1992/3/1

N2 - An investigation was conducted to compare the rates and mechanisms of epoxy-amine reactions in thermal and microwave fields. A monofunctional model compound formulation and a multifunctional epoxy formulation were analyzed. Chromatographic, spectroscopic, and calorimetric techniques were utilized to generate data. Excellent agreement was observed between the proposed mechanistic model and experimental results. It was unequivocally found that the use of microwave energy in lieu of thermal energy had no effect on the reaction kinetics.

AB - An investigation was conducted to compare the rates and mechanisms of epoxy-amine reactions in thermal and microwave fields. A monofunctional model compound formulation and a multifunctional epoxy formulation were analyzed. Chromatographic, spectroscopic, and calorimetric techniques were utilized to generate data. Excellent agreement was observed between the proposed mechanistic model and experimental results. It was unequivocally found that the use of microwave energy in lieu of thermal energy had no effect on the reaction kinetics.

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Mechanistic Modeling of Epoxy-Amine Kinetics. 2. Comparison of Kinetics in Thermal and Microwave Fields

Abstract

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