Metal-catalyzed silylene transfer to imines: Synthesis and reactivity of silaaziridines

Zulimar Nevárez; K. A. Woerpel

doi:10.1021/ol701424a

Metal-catalyzed silylene transfer to imines: Synthesis and reactivity of silaaziridines

Zulimar Nevárez, K. A. Woerpel

Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

Metal-catalyzed silylene transfer to imines provides an efficient synthesis of silaaziridines. These strained cyclic silanes undergo selective bond-forming reactions, permitting the synthesis of nitrogen-containing compounds after protodesilylation of the resulting vinyl silane.

Original language	English (US)
Pages (from-to)	3773-3776
Number of pages	4
Journal	Organic Letters
Volume	9
Issue number	19
DOIs	https://doi.org/10.1021/ol701424a
State	Published - Sep 13 2007

ASJC Scopus subject areas

Biochemistry
Physical and Theoretical Chemistry
Organic Chemistry

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title = "Metal-catalyzed silylene transfer to imines: Synthesis and reactivity of silaaziridines",

abstract = "Metal-catalyzed silylene transfer to imines provides an efficient synthesis of silaaziridines. These strained cyclic silanes undergo selective bond-forming reactions, permitting the synthesis of nitrogen-containing compounds after protodesilylation of the resulting vinyl silane.",

author = "Zulimar Nev{\'a}rez and Woerpel, {K. A.}",

year = "2007",

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Y1 - 2007/9/13

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AB - Metal-catalyzed silylene transfer to imines provides an efficient synthesis of silaaziridines. These strained cyclic silanes undergo selective bond-forming reactions, permitting the synthesis of nitrogen-containing compounds after protodesilylation of the resulting vinyl silane.

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JO - Organic Letters

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Metal-catalyzed silylene transfer to imines: Synthesis and reactivity of silaaziridines

Abstract

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