Metal templated receptors for the effective complexation of dicarboxylates

M. Scott Goodman; Vrej Jubian; Andrew D. Hamilton

doi:10.1016/0040-4039(95)00337-C

Metal templated receptors for the effective complexation of dicarboxylates

M. Scott Goodman, Vrej Jubian, Andrew D. Hamilton

Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

In this paper we show that a thiourea-functionalized terpyridine unit can be induced to form, in the presence of ruthenium (II), a well-ordered recognition site for dicarboxylate ions. Strong binding to the self-assembled receptor can be followed by ¹H NMR in DMSO and association constants of >10⁴ M^-1 were measured in certain cases.

Original language	English (US)
Pages (from-to)	2551-2554
Number of pages	4
Journal	Tetrahedron Letters
Volume	36
Issue number	15
DOIs	https://doi.org/10.1016/0040-4039(95)00337-C
State	Published - Apr 10 1995

ASJC Scopus subject areas

Biochemistry
Drug Discovery
Organic Chemistry

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10.1016/0040-4039(95)00337-C

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abstract = "In this paper we show that a thiourea-functionalized terpyridine unit can be induced to form, in the presence of ruthenium (II), a well-ordered recognition site for dicarboxylate ions. Strong binding to the self-assembled receptor can be followed by 1H NMR in DMSO and association constants of >104 M-1 were measured in certain cases.",

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AB - In this paper we show that a thiourea-functionalized terpyridine unit can be induced to form, in the presence of ruthenium (II), a well-ordered recognition site for dicarboxylate ions. Strong binding to the self-assembled receptor can be followed by 1H NMR in DMSO and association constants of >104 M-1 were measured in certain cases.

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Metal templated receptors for the effective complexation of dicarboxylates

Abstract

ASJC Scopus subject areas

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