Micelle-based nanoreactors containing Ru-porphyrin for the epoxidation of terminal olefins in water

Jie Lu; Linus Liang; Marcus Weck

doi:10.1016/j.molcata.2016.02.033

Micelle-based nanoreactors containing Ru-porphyrin for the epoxidation of terminal olefins in water

Jie Lu, Linus Liang, Marcus Weck

Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

This contribution introduces a strategy to use Ru(II)-porphyrin complexes as catalysts for the epoxidation of alkenes in water. The design is based on shell cross-linked micelle-based nanoreactors with hydrophobic cores and hydrophilic shells as supports for the Ru(II) porphyrin complexes. The supported complexes are efficient catalysts for oxidation reactions, specifically the selectively oxidation of alkenes to epoxides. The presented strategy is the first system that allows for running Ru-catalyzed epoxidation reactions in water.

Original language	English (US)
Pages (from-to)	122-125
Number of pages	4
Journal	Journal of Molecular Catalysis A: Chemical
Volume	417
DOIs	https://doi.org/10.1016/j.molcata.2016.02.033
State	Published - Jun 1 2016

Keywords

Epoxidation
Ruthenium
Supported catalysis

ASJC Scopus subject areas

Catalysis
Process Chemistry and Technology
Physical and Theoretical Chemistry

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10.1016/j.molcata.2016.02.033

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title = "Micelle-based nanoreactors containing Ru-porphyrin for the epoxidation of terminal olefins in water",

abstract = "This contribution introduces a strategy to use Ru(II)-porphyrin complexes as catalysts for the epoxidation of alkenes in water. The design is based on shell cross-linked micelle-based nanoreactors with hydrophobic cores and hydrophilic shells as supports for the Ru(II) porphyrin complexes. The supported complexes are efficient catalysts for oxidation reactions, specifically the selectively oxidation of alkenes to epoxides. The presented strategy is the first system that allows for running Ru-catalyzed epoxidation reactions in water.",

keywords = "Epoxidation, Ruthenium, Supported catalysis",

author = "Jie Lu and Linus Liang and Marcus Weck",

year = "2016",

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language = "English (US)",

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T1 - Micelle-based nanoreactors containing Ru-porphyrin for the epoxidation of terminal olefins in water

AU - Lu, Jie

AU - Liang, Linus

AU - Weck, Marcus

PY - 2016/6/1

Y1 - 2016/6/1

N2 - This contribution introduces a strategy to use Ru(II)-porphyrin complexes as catalysts for the epoxidation of alkenes in water. The design is based on shell cross-linked micelle-based nanoreactors with hydrophobic cores and hydrophilic shells as supports for the Ru(II) porphyrin complexes. The supported complexes are efficient catalysts for oxidation reactions, specifically the selectively oxidation of alkenes to epoxides. The presented strategy is the first system that allows for running Ru-catalyzed epoxidation reactions in water.

AB - This contribution introduces a strategy to use Ru(II)-porphyrin complexes as catalysts for the epoxidation of alkenes in water. The design is based on shell cross-linked micelle-based nanoreactors with hydrophobic cores and hydrophilic shells as supports for the Ru(II) porphyrin complexes. The supported complexes are efficient catalysts for oxidation reactions, specifically the selectively oxidation of alkenes to epoxides. The presented strategy is the first system that allows for running Ru-catalyzed epoxidation reactions in water.

KW - Epoxidation

KW - Ruthenium

KW - Supported catalysis

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M3 - Article

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SN - 1381-1169

VL - 417

SP - 122

EP - 125

JO - Journal of Molecular Catalysis A: Chemical

JF - Journal of Molecular Catalysis A: Chemical

ER -

Micelle-based nanoreactors containing Ru-porphyrin for the epoxidation of terminal olefins in water

Abstract

Keywords

ASJC Scopus subject areas

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