A hydrogen-bonding receptor containing an appended thiol has been synthesized and shown to cause large rate accelerations (kobs/k uncat > 104) in the thiolysis reaction of complementary barbiturate acetate derivatives.
|Original language||English (US)|
|Number of pages||3|
|Journal||Journal of the Chemical Society, Chemical Communications|
|State||Published - 1990|
ASJC Scopus subject areas
- Molecular Medicine