Monolayers Having Large In-Plane Dipole Moments: Characterization of Sulfone-Containing Self-Assembled Monolayers of Alkanethiols on Gold by Fourier Transform Infrared Spectroscopy, X-ray Photoelectron Spectroscopy, and Wetting

Kim E. Goppert-Berarducci; Edward Urankar; Louis J. Gerenser; Abraham Ulman; Robert G. Snyder

doi:10.1021/la00059a050

Monolayers Having Large In-Plane Dipole Moments: Characterization of Sulfone-Containing Self-Assembled Monolayers of Alkanethiols on Gold by Fourier Transform Infrared Spectroscopy, X-ray Photoelectron Spectroscopy, and Wetting

Kim E. Goppert-Berarducci, Edward Urankar, Louis J. Gerenser, Abraham Ulman, Robert G. Snyder

Chemical and Biomolecular Engineering

Research output: Contribution to journal › Article › peer-review

Abstract

Monolayers were formed from alkyl chain molecules having large in-plane dipole moments. The molecular species introduced was a sulfone moiety, and it was found that its incorporation strongly affected the molecular conformation within the monolayer. The effect of varying the position of the sulfone group in an otherwise straight alkyl chain, while constant molecular length was maintained, was studied, and the results were compared to those found for an octadecanethiol (ODT). The monolayers were characterized by Fourier transform infrared reflection absorption spectroscopy and X-ray photoelectron spectroscopy and by their wetting properties.

Original language	English (US)
Pages (from-to)	2700-2709
Number of pages	10
Journal	Langmuir
Volume	7
Issue number	11
DOIs	https://doi.org/10.1021/la00059a050
State	Published - Nov 1 1991

ASJC Scopus subject areas

General Materials Science
Condensed Matter Physics
Surfaces and Interfaces
Spectroscopy
Electrochemistry

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Goppert-Berarducci, K. E., Urankar, E., Gerenser, L. J., Ulman, A., & Snyder, R. G. (1991). Monolayers Having Large In-Plane Dipole Moments: Characterization of Sulfone-Containing Self-Assembled Monolayers of Alkanethiols on Gold by Fourier Transform Infrared Spectroscopy, X-ray Photoelectron Spectroscopy, and Wetting. Langmuir, 7(11), 2700-2709. https://doi.org/10.1021/la00059a050

Monolayers Having Large In-Plane Dipole Moments: Characterization of Sulfone-Containing Self-Assembled Monolayers of Alkanethiols on Gold by Fourier Transform Infrared Spectroscopy, X-ray Photoelectron Spectroscopy, and Wetting. / Goppert-Berarducci, Kim E.; Urankar, Edward; Gerenser, Louis J. et al.
In: Langmuir, Vol. 7, No. 11, 01.11.1991, p. 2700-2709.

Research output: Contribution to journal › Article › peer-review

Goppert-Berarducci, KE, Urankar, E, Gerenser, LJ, Ulman, A & Snyder, RG 1991, 'Monolayers Having Large In-Plane Dipole Moments: Characterization of Sulfone-Containing Self-Assembled Monolayers of Alkanethiols on Gold by Fourier Transform Infrared Spectroscopy, X-ray Photoelectron Spectroscopy, and Wetting', Langmuir, vol. 7, no. 11, pp. 2700-2709. https://doi.org/10.1021/la00059a050

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abstract = "Monolayers were formed from alkyl chain molecules having large in-plane dipole moments. The molecular species introduced was a sulfone moiety, and it was found that its incorporation strongly affected the molecular conformation within the monolayer. The effect of varying the position of the sulfone group in an otherwise straight alkyl chain, while constant molecular length was maintained, was studied, and the results were compared to those found for an octadecanethiol (ODT). The monolayers were characterized by Fourier transform infrared reflection absorption spectroscopy and X-ray photoelectron spectroscopy and by their wetting properties.",

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Monolayers Having Large In-Plane Dipole Moments: Characterization of Sulfone-Containing Self-Assembled Monolayers of Alkanethiols on Gold by Fourier Transform Infrared Spectroscopy, X-ray Photoelectron Spectroscopy, and Wetting

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