TY - JOUR
T1 - Observation of bulk phase separation and coexistence in a sheared micellar solution
AU - Boltenhagen, Philippe
AU - Hu, Yuntao
AU - Matthys, E. F.
AU - Pine, D. J.
PY - 1997
Y1 - 1997
N2 - We observe a shear-flow-induced phase transition in wormlike micelle solutions which depends on whether the applied stress or the applied shear rate is held constant. When the shear stress is held constant, the system macroscopically phase separates into two coexisting phases with a single stable interface between them. By contrast, when the shear rate is held constant, the system still undergoes a phase transition, but the steady states are homogeneous and no coexistence is observed. This leads to dramatically different rheological behavior and unusual long-lived metastable states.
AB - We observe a shear-flow-induced phase transition in wormlike micelle solutions which depends on whether the applied stress or the applied shear rate is held constant. When the shear stress is held constant, the system macroscopically phase separates into two coexisting phases with a single stable interface between them. By contrast, when the shear rate is held constant, the system still undergoes a phase transition, but the steady states are homogeneous and no coexistence is observed. This leads to dramatically different rheological behavior and unusual long-lived metastable states.
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U2 - 10.1103/PhysRevLett.79.2359
DO - 10.1103/PhysRevLett.79.2359
M3 - Article
AN - SCOPUS:0000060839
SN - 0031-9007
VL - 79
SP - 2359
EP - 2362
JO - Physical Review Letters
JF - Physical Review Letters
IS - 12
ER -