On microphase segregation of interpenetrating polymer networks

Harry L. Frisch; Alexander Yu Grosberg

doi:10.1002/mats.1993.040020401

On microphase segregation of interpenetrating polymer networks

Harry L. Frisch, Alexander Yu Grosberg

Research output: Contribution to journal › Article › peer-review

Abstract

The topological entanglements between subchains of two interpenetrating polymer networks are described in the simplest approximation supposing that the primitive path of each subchain is influenced due to the shift of one network relatively to the other. The entanglement contribution to the free energy of the networks is shown to behave as 1/q² for the state with deviation from uniform densities with the wave vector of order q. This contribution is shown to cause the microphase type of segregation.

Original language	English (US)
Pages (from-to)	517-522
Number of pages	6
Journal	Macromolecular Theory and Simulations
Volume	2
Issue number	4
DOIs	https://doi.org/10.1002/mats.1993.040020401
State	Published - Jun 1993

ASJC Scopus subject areas

Condensed Matter Physics
Organic Chemistry
Polymers and Plastics
Inorganic Chemistry
Materials Chemistry

Access to Document

10.1002/mats.1993.040020401

Cite this

@article{05953bef264d446d9111d8796e26a0f9,

title = "On microphase segregation of interpenetrating polymer networks",

abstract = "The topological entanglements between subchains of two interpenetrating polymer networks are described in the simplest approximation supposing that the primitive path of each subchain is influenced due to the shift of one network relatively to the other. The entanglement contribution to the free energy of the networks is shown to behave as 1/q2 for the state with deviation from uniform densities with the wave vector of order q. This contribution is shown to cause the microphase type of segregation.",

author = "Frisch, {Harry L.} and Grosberg, {Alexander Yu}",

year = "1993",

month = jun,

doi = "10.1002/mats.1993.040020401",

language = "English (US)",

volume = "2",

pages = "517--522",

journal = "Macromolecular Theory and Simulations",

issn = "1022-1344",

publisher = "Wiley-VCH Verlag",

number = "4",

}

TY - JOUR

T1 - On microphase segregation of interpenetrating polymer networks

AU - Frisch, Harry L.

AU - Grosberg, Alexander Yu

PY - 1993/6

Y1 - 1993/6

N2 - The topological entanglements between subchains of two interpenetrating polymer networks are described in the simplest approximation supposing that the primitive path of each subchain is influenced due to the shift of one network relatively to the other. The entanglement contribution to the free energy of the networks is shown to behave as 1/q2 for the state with deviation from uniform densities with the wave vector of order q. This contribution is shown to cause the microphase type of segregation.

AB - The topological entanglements between subchains of two interpenetrating polymer networks are described in the simplest approximation supposing that the primitive path of each subchain is influenced due to the shift of one network relatively to the other. The entanglement contribution to the free energy of the networks is shown to behave as 1/q2 for the state with deviation from uniform densities with the wave vector of order q. This contribution is shown to cause the microphase type of segregation.

UR - http://www.scopus.com/inward/record.url?scp=84981461800&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=84981461800&partnerID=8YFLogxK

U2 - 10.1002/mats.1993.040020401

DO - 10.1002/mats.1993.040020401

M3 - Article

AN - SCOPUS:84981461800

SN - 1022-1344

VL - 2

SP - 517

EP - 522

JO - Macromolecular Theory and Simulations

JF - Macromolecular Theory and Simulations

IS - 4

ER -

On microphase segregation of interpenetrating polymer networks

Abstract

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Cite this