On the short carbonyl bond in bis[μ-1, 2-benzisothiazol-3(2H)-one 1, 1-dioxido-κ2N:O] bis([1, 2-benzisothiazol-3(2H)-one 1, 1-dioxido-κN]-bis(imidazole)copper(II))

P. Naumov; G. Jovanovski; S. Z. Hu; I. H. Suh; I. A. Razak; S. Chantrapromma; H. K. Fun; S. W. Ng

doi:10.1107/S0108270101009507

On the short carbonyl bond in bis[μ-1, 2-benzisothiazol-3(2H)-one 1, 1-dioxido-κ²N:O] bis([1, 2-benzisothiazol-3(2H)-one 1, 1-dioxido-κN]-bis(imidazole)copper(II))

P. Naumov, G. Jovanovski, S. Z. Hu, I. H. Suh, I. A. Razak, S. Chantrapromma, H. K. Fun, S. W. Ng

Chemistry

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Abstract

The short carbonyl bond in the title compound, [Cu₂(C₇H₄NO₃S)₄ (C₃H₄N₂)₄] [Liu, Huang, Li & Lin (1991). Acta Cryst. C47, 41-43], is an artifact of disorder in the isothiazol-3(2H)one 1, 1-dioxide part of the 1, 2-benzisothiazol-3(2H)-one entity. In the present redetermination, all bond dimensions in the centrosymmetric dinuclear molecule are normal. The five-coordinate Cu atom shows trigonal-bipyramidal coordination. Hydrogen bonds from the imidazole donor ligand link adjacent molecules into a two-dimensional layer structure.

Original language	English (US)
Pages (from-to)	1016-1019
Number of pages	4
Journal	Acta Crystallographica Section C: Crystal Structure Communications
Volume	57
Issue number	9
DOIs	https://doi.org/10.1107/S0108270101009507
State	Published - Sep 2001

ASJC Scopus subject areas

General Biochemistry, Genetics and Molecular Biology

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Naumov, P., Jovanovski, G., Hu, S. Z., Suh, I. H., Razak, I. A., Chantrapromma, S., Fun, H. K., & Ng, S. W. (2001). On the short carbonyl bond in bis[μ-1, 2-benzisothiazol-3(2H)-one 1, 1-dioxido-κ²N:O] bis([1, 2-benzisothiazol-3(2H)-one 1, 1-dioxido-κN]-bis(imidazole)copper(II)). Acta Crystallographica Section C: Crystal Structure Communications, 57(9), 1016-1019. https://doi.org/10.1107/S0108270101009507

On the short carbonyl bond in bis[μ-1, 2-benzisothiazol-3(2H)-one 1, 1-dioxido-κ²N:O] bis([1, 2-benzisothiazol-3(2H)-one 1, 1-dioxido-κN]-bis(imidazole)copper(II)). / Naumov, P.; Jovanovski, G.; Hu, S. Z. et al.
In: Acta Crystallographica Section C: Crystal Structure Communications, Vol. 57, No. 9, 09.2001, p. 1016-1019.

Research output: Contribution to journal › Article › peer-review

Naumov, P, Jovanovski, G, Hu, SZ, Suh, IH, Razak, IA, Chantrapromma, S, Fun, HK & Ng, SW 2001, 'On the short carbonyl bond in bis[μ-1, 2-benzisothiazol-3(2H)-one 1, 1-dioxido-κ²N:O] bis([1, 2-benzisothiazol-3(2H)-one 1, 1-dioxido-κN]-bis(imidazole)copper(II))', Acta Crystallographica Section C: Crystal Structure Communications, vol. 57, no. 9, pp. 1016-1019. https://doi.org/10.1107/S0108270101009507

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title = "On the short carbonyl bond in bis[μ-1, 2-benzisothiazol-3(2H)-one 1, 1-dioxido-κ2N:O] bis([1, 2-benzisothiazol-3(2H)-one 1, 1-dioxido-κN]-bis(imidazole)copper(II))",

abstract = "The short carbonyl bond in the title compound, [Cu2(C7H4NO3S)4 (C3H4N2)4] [Liu, Huang, Li & Lin (1991). Acta Cryst. C47, 41-43], is an artifact of disorder in the isothiazol-3(2H)one 1, 1-dioxide part of the 1, 2-benzisothiazol-3(2H)-one entity. In the present redetermination, all bond dimensions in the centrosymmetric dinuclear molecule are normal. The five-coordinate Cu atom shows trigonal-bipyramidal coordination. Hydrogen bonds from the imidazole donor ligand link adjacent molecules into a two-dimensional layer structure.",

author = "P. Naumov and G. Jovanovski and Hu, {S. Z.} and Suh, {I. H.} and Razak, {I. A.} and S. Chantrapromma and Fun, {H. K.} and Ng, {S. W.}",

year = "2001",

month = sep,

doi = "10.1107/S0108270101009507",

language = "English (US)",

volume = "57",

pages = "1016--1019",

journal = "Acta Crystallographica Section C: Crystal Structure Communications",

issn = "0108-2701",

publisher = "International Union of Crystallography",

number = "9",

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TY - JOUR

T1 - On the short carbonyl bond in bis[μ-1, 2-benzisothiazol-3(2H)-one 1, 1-dioxido-κ2N:O] bis([1, 2-benzisothiazol-3(2H)-one 1, 1-dioxido-κN]-bis(imidazole)copper(II))

AU - Naumov, P.

AU - Jovanovski, G.

AU - Hu, S. Z.

AU - Suh, I. H.

AU - Razak, I. A.

AU - Chantrapromma, S.

AU - Fun, H. K.

AU - Ng, S. W.

PY - 2001/9

Y1 - 2001/9

N2 - The short carbonyl bond in the title compound, [Cu2(C7H4NO3S)4 (C3H4N2)4] [Liu, Huang, Li & Lin (1991). Acta Cryst. C47, 41-43], is an artifact of disorder in the isothiazol-3(2H)one 1, 1-dioxide part of the 1, 2-benzisothiazol-3(2H)-one entity. In the present redetermination, all bond dimensions in the centrosymmetric dinuclear molecule are normal. The five-coordinate Cu atom shows trigonal-bipyramidal coordination. Hydrogen bonds from the imidazole donor ligand link adjacent molecules into a two-dimensional layer structure.

AB - The short carbonyl bond in the title compound, [Cu2(C7H4NO3S)4 (C3H4N2)4] [Liu, Huang, Li & Lin (1991). Acta Cryst. C47, 41-43], is an artifact of disorder in the isothiazol-3(2H)one 1, 1-dioxide part of the 1, 2-benzisothiazol-3(2H)-one entity. In the present redetermination, all bond dimensions in the centrosymmetric dinuclear molecule are normal. The five-coordinate Cu atom shows trigonal-bipyramidal coordination. Hydrogen bonds from the imidazole donor ligand link adjacent molecules into a two-dimensional layer structure.

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U2 - 10.1107/S0108270101009507

DO - 10.1107/S0108270101009507

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C2 - 11588355

AN - SCOPUS:0035437825

SN - 0108-2701

VL - 57

SP - 1016

EP - 1019

JO - Acta Crystallographica Section C: Crystal Structure Communications

JF - Acta Crystallographica Section C: Crystal Structure Communications

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ER -

On the short carbonyl bond in bis[μ-1, 2-benzisothiazol-3(2H)-one 1, 1-dioxido-κ²N:O] bis([1, 2-benzisothiazol-3(2H)-one 1, 1-dioxido-κN]-bis(imidazole)copper(II))

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