One-Step Multifunctionalization of Random Copolymers via Self-Assembly

Joel M. Pollino; Ludger P. Stubbs; Marcus Weck

doi:10.1021/ja0372715

One-Step Multifunctionalization of Random Copolymers via Self-Assembly

Joel M. Pollino, Ludger P. Stubbs, Marcus Weck

Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

A novel methodology for random copolymer functionalization based on a noncovalent, one-step, multifunctionalization strategy has been developed. Random copolymers possessing both palladated-pincer complexes and diaminopyridine moieties (hydrogen-bonding entities) have been synthesized using ring-opening metathesis polymerization. Noncovalent functionalization of the resultant copolymers is accomplished via (1) directed self-assembly, (2) multistep self-assembly, and (3) one-step orthogonal self-assembly. This system shows complete specificity of each recognition motif for its complementary unit, with no observable changes in the association constants regardless of the degree of functionalization.

Original language	English (US)
Pages (from-to)	563-567
Number of pages	5
Journal	Journal of the American Chemical Society
Volume	126
Issue number	2
DOIs	https://doi.org/10.1021/ja0372715
State	Published - Jan 21 2004

ASJC Scopus subject areas

Catalysis
General Chemistry
Biochemistry
Colloid and Surface Chemistry

Access to Document

10.1021/ja0372715

Cite this

@article{7093d932c1ac47e5b69a5f21048a2b75,

title = "One-Step Multifunctionalization of Random Copolymers via Self-Assembly",

abstract = "A novel methodology for random copolymer functionalization based on a noncovalent, one-step, multifunctionalization strategy has been developed. Random copolymers possessing both palladated-pincer complexes and diaminopyridine moieties (hydrogen-bonding entities) have been synthesized using ring-opening metathesis polymerization. Noncovalent functionalization of the resultant copolymers is accomplished via (1) directed self-assembly, (2) multistep self-assembly, and (3) one-step orthogonal self-assembly. This system shows complete specificity of each recognition motif for its complementary unit, with no observable changes in the association constants regardless of the degree of functionalization.",

author = "Pollino, {Joel M.} and Stubbs, {Ludger P.} and Marcus Weck",

year = "2004",

month = jan,

day = "21",

doi = "10.1021/ja0372715",

language = "English (US)",

volume = "126",

pages = "563--567",

journal = "Journal of the American Chemical Society",

issn = "0002-7863",

publisher = "American Chemical Society",

number = "2",

}

TY - JOUR

T1 - One-Step Multifunctionalization of Random Copolymers via Self-Assembly

AU - Pollino, Joel M.

AU - Stubbs, Ludger P.

AU - Weck, Marcus

PY - 2004/1/21

Y1 - 2004/1/21

N2 - A novel methodology for random copolymer functionalization based on a noncovalent, one-step, multifunctionalization strategy has been developed. Random copolymers possessing both palladated-pincer complexes and diaminopyridine moieties (hydrogen-bonding entities) have been synthesized using ring-opening metathesis polymerization. Noncovalent functionalization of the resultant copolymers is accomplished via (1) directed self-assembly, (2) multistep self-assembly, and (3) one-step orthogonal self-assembly. This system shows complete specificity of each recognition motif for its complementary unit, with no observable changes in the association constants regardless of the degree of functionalization.

AB - A novel methodology for random copolymer functionalization based on a noncovalent, one-step, multifunctionalization strategy has been developed. Random copolymers possessing both palladated-pincer complexes and diaminopyridine moieties (hydrogen-bonding entities) have been synthesized using ring-opening metathesis polymerization. Noncovalent functionalization of the resultant copolymers is accomplished via (1) directed self-assembly, (2) multistep self-assembly, and (3) one-step orthogonal self-assembly. This system shows complete specificity of each recognition motif for its complementary unit, with no observable changes in the association constants regardless of the degree of functionalization.

UR - http://www.scopus.com/inward/record.url?scp=0345825804&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=0345825804&partnerID=8YFLogxK

U2 - 10.1021/ja0372715

DO - 10.1021/ja0372715

M3 - Article

C2 - 14719954

AN - SCOPUS:0345825804

SN - 0002-7863

VL - 126

SP - 563

EP - 567

JO - Journal of the American Chemical Society

JF - Journal of the American Chemical Society

IS - 2

ER -

One-Step Multifunctionalization of Random Copolymers via Self-Assembly

Abstract

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Cite this