Optical rotation of achiral pentaerythritol

Kacey Claborn, Javier Herreros Cedres, Christine Isborn, Alexey Zozulya, Edgar Weckert, Werner Kaminsky, Bart Kahr

Research output: Contribution to journalArticlepeer-review

Abstract

The optical rotatory power of achiral crystals of achiral pentaerythritol molecules was measured. The maximum rotations were found to be ±6°/mm. The quantum mechanically computed rotation of pentaerythritol molecules using linear response theory was 6 times larger although the experimental and theoretical tensors were similarly oriented to within 5°.

Original languageEnglish (US)
Pages (from-to)14746-14747
Number of pages2
JournalJournal of the American Chemical Society
Volume128
Issue number46
DOIs
StatePublished - Nov 22 2006

ASJC Scopus subject areas

  • Catalysis
  • Chemistry(all)
  • Biochemistry
  • Colloid and Surface Chemistry

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