Optically pumped dynamic nuclear hyperpolarization in C 13 -enriched diamond

Anna J. Parker; Keunhong Jeong; Claudia E. Avalos; Birgit J.M. Hausmann; Christophoros C. Vassiliou; Alexander Pines; Jonathan P. King

doi:10.1103/PhysRevB.100.041203

Optically pumped dynamic nuclear hyperpolarization in C 13 -enriched diamond

Anna J. Parker, Keunhong Jeong, Claudia E. Avalos, Birgit J.M. Hausmann, Christophoros C. Vassiliou, Alexander Pines, Jonathan P. King

Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

We investigate nuclear spin hyperpolarization from optically polarized nitrogen vacancy centers in isotopically enriched diamonds with C13 concentrations up to 100%. C13 enrichment leads to a nitrogen vacancy electron spin resonance with a complex hyperfine structure and dynamic nuclear polarization enhancement profile. We show that strongly coupled C13 spins in the first shell surrounding a nitrogen vacancy center generate resolved hyperfine splittings, but do not act as an intermediary in the transfer of hyperpolarization of bulk nuclear spins. High levels of C13 enrichment are desirable to increase the efficiency of hyperpolarization for magnetic resonance signal enhancement, imaging contrast agents, and as a platform for quantum sensing and many-body physics.

Original language	English (US)
Article number	041203
Journal	Physical Review B
Volume	100
Issue number	4
DOIs	https://doi.org/10.1103/PhysRevB.100.041203
State	Published - Jul 30 2019

ASJC Scopus subject areas

Electronic, Optical and Magnetic Materials
Condensed Matter Physics

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10.1103/PhysRevB.100.041203

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title = "Optically pumped dynamic nuclear hyperpolarization in C 13 -enriched diamond",

abstract = "We investigate nuclear spin hyperpolarization from optically polarized nitrogen vacancy centers in isotopically enriched diamonds with C13 concentrations up to 100%. C13 enrichment leads to a nitrogen vacancy electron spin resonance with a complex hyperfine structure and dynamic nuclear polarization enhancement profile. We show that strongly coupled C13 spins in the first shell surrounding a nitrogen vacancy center generate resolved hyperfine splittings, but do not act as an intermediary in the transfer of hyperpolarization of bulk nuclear spins. High levels of C13 enrichment are desirable to increase the efficiency of hyperpolarization for magnetic resonance signal enhancement, imaging contrast agents, and as a platform for quantum sensing and many-body physics.",

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AU - Parker, Anna J.

AU - Jeong, Keunhong

AU - Avalos, Claudia E.

AU - Hausmann, Birgit J.M.

AU - Vassiliou, Christophoros C.

AU - Pines, Alexander

AU - King, Jonathan P.

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AB - We investigate nuclear spin hyperpolarization from optically polarized nitrogen vacancy centers in isotopically enriched diamonds with C13 concentrations up to 100%. C13 enrichment leads to a nitrogen vacancy electron spin resonance with a complex hyperfine structure and dynamic nuclear polarization enhancement profile. We show that strongly coupled C13 spins in the first shell surrounding a nitrogen vacancy center generate resolved hyperfine splittings, but do not act as an intermediary in the transfer of hyperpolarization of bulk nuclear spins. High levels of C13 enrichment are desirable to increase the efficiency of hyperpolarization for magnetic resonance signal enhancement, imaging contrast agents, and as a platform for quantum sensing and many-body physics.

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Optically pumped dynamic nuclear hyperpolarization in C 13 -enriched diamond

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