Oxidative radical cyclizations of diketopiperazines bearing an amidomalonate unit. Heterointermediate reaction sequences toward the asperparalines and stephacidins

Chemistry

• Primary Structure 100%
• Radical Cyclization 100%
• Stereochemistry 50%
• Time Evolving Matrix Product Operator 50%
• Octane 50%
• Oxidative Cyclization 50%

Keyphrases

• Persistent Radicals 33%
• Divergent Reaction 33%
• Diketopiperazine Alkaloids 33%
• Oxidation Condition 33%
• Cu(OTf)2 33%
• Ferrocenium 33%

Pharmacology, Toxicology and Pharmaceutical Science

• Piperazinedione 100%
• Hexafluorophosphate 25%