Palladium-Loaded Cucurbit[7]uril-Modified Iron Oxide Nanoparticles for C−C Cross-Coupling Reactions

Farah Benyettou; Laurence Motte; Hassan Traboulsi; Javed Mazher; Renu Pasricha; John Carl Olsen; Ali Trabolsi; Erwan Guenin

doi:10.1002/chem.201705082

Palladium-Loaded Cucurbit[7]uril-Modified Iron Oxide Nanoparticles for C−C Cross-Coupling Reactions

Farah Benyettou, Laurence Motte, Hassan Traboulsi, Javed Mazher, Renu Pasricha, John Carl Olsen, Ali Trabolsi, Erwan Guenin

Research output: Contribution to journal › Article › peer-review

Abstract

Cucurbit[7]uril modified iron oxide nanoparticles (CB[7]NPs) were loaded with palladium to form nano-catalysts (Pd@CB[7]NPs) that, with microwave heating, catalysed Suzuki–Miyaura, Sonogashira, and Mizoroki–Heck cross-coupling reactions. Reactions were run in environmentally benign 1:1 ethanol/water solvent under convenient aerobic conditions. In a preliminary screening, conversions and yields were uniformly high with turn over frequencies (TOF) ranging from 64 to 7360 h⁻¹. The nano-catalysts could be recovered with a magnet and reused several times (6 times for Suzuki–Miayura reaction) without loss of activity.

Original language	English (US)
Pages (from-to)	2349-2353
Number of pages	5
Journal	Chemistry - A European Journal
Volume	24
Issue number	10
DOIs	https://doi.org/10.1002/chem.201705082
State	Published - Feb 16 2018

Keywords

cross-coupling reactions
cucurbit[7]uril
macrocyclic chemistry
magnetic nano-catalyst
palladium

ASJC Scopus subject areas

Catalysis
Organic Chemistry

Access to Document

10.1002/chem.201705082

Cite this

Palladium-Loaded Cucurbit[7]uril-Modified Iron Oxide Nanoparticles for C−C Cross-Coupling Reactions. / Benyettou, Farah; Motte, Laurence; Traboulsi, Hassan; Mazher, Javed; Pasricha, Renu; Olsen, John Carl; Trabolsi, Ali; Guenin, Erwan.

In: Chemistry - A European Journal, Vol. 24, No. 10, 16.02.2018, p. 2349-2353.

Research output: Contribution to journal › Article › peer-review

@article{6066f58d939e44d985c0f124983ae1cc,

title = "Palladium-Loaded Cucurbit[7]uril-Modified Iron Oxide Nanoparticles for C−C Cross-Coupling Reactions",

abstract = "Cucurbit[7]uril modified iron oxide nanoparticles (CB[7]NPs) were loaded with palladium to form nano-catalysts (Pd@CB[7]NPs) that, with microwave heating, catalysed Suzuki–Miyaura, Sonogashira, and Mizoroki–Heck cross-coupling reactions. Reactions were run in environmentally benign 1:1 ethanol/water solvent under convenient aerobic conditions. In a preliminary screening, conversions and yields were uniformly high with turn over frequencies (TOF) ranging from 64 to 7360 h−1. The nano-catalysts could be recovered with a magnet and reused several times (6 times for Suzuki–Miayura reaction) without loss of activity.",

keywords = "cross-coupling reactions, cucurbit[7]uril, macrocyclic chemistry, magnetic nano-catalyst, palladium",

author = "Farah Benyettou and Laurence Motte and Hassan Traboulsi and Javed Mazher and Renu Pasricha and Olsen, {John Carl} and Ali Trabolsi and Erwan Guenin",

note = "Funding Information: This research was sponsored by the European Union, the R{\'e}gion Haut de France, the Ecole Sup{\'e}rieur de Chimie Orga-nique et Min{\'e}rale (ESCOM) and Universit{\'e} de Technologie de Compi{\`e}gne (UTC) through FEDER funding of the chair: “Green Chemistry and Processes”. The research was also sponsored by New York University Abu Dhabi (NYUAD) and carried out by using the NYUAD Core Technology Platform resources. F.B., R.P. and A.T. thank NYUAD for their generous support. We would also like to acknowledge the Al Jalila Foundation for financial support (AJF201538).",

year = "2018",

month = feb,

day = "16",

doi = "10.1002/chem.201705082",

language = "English (US)",

volume = "24",

pages = "2349--2353",

journal = "Chemistry - A European Journal",

issn = "0947-6539",

publisher = "Wiley-VCH Verlag",

number = "10",

}

TY - JOUR

T1 - Palladium-Loaded Cucurbit[7]uril-Modified Iron Oxide Nanoparticles for C−C Cross-Coupling Reactions

AU - Benyettou, Farah

AU - Motte, Laurence

AU - Traboulsi, Hassan

AU - Mazher, Javed

AU - Pasricha, Renu

AU - Olsen, John Carl

AU - Trabolsi, Ali

AU - Guenin, Erwan

N1 - Funding Information: This research was sponsored by the European Union, the Région Haut de France, the Ecole Supérieur de Chimie Orga-nique et Minérale (ESCOM) and Université de Technologie de Compiègne (UTC) through FEDER funding of the chair: “Green Chemistry and Processes”. The research was also sponsored by New York University Abu Dhabi (NYUAD) and carried out by using the NYUAD Core Technology Platform resources. F.B., R.P. and A.T. thank NYUAD for their generous support. We would also like to acknowledge the Al Jalila Foundation for financial support (AJF201538).

PY - 2018/2/16

Y1 - 2018/2/16

N2 - Cucurbit[7]uril modified iron oxide nanoparticles (CB[7]NPs) were loaded with palladium to form nano-catalysts (Pd@CB[7]NPs) that, with microwave heating, catalysed Suzuki–Miyaura, Sonogashira, and Mizoroki–Heck cross-coupling reactions. Reactions were run in environmentally benign 1:1 ethanol/water solvent under convenient aerobic conditions. In a preliminary screening, conversions and yields were uniformly high with turn over frequencies (TOF) ranging from 64 to 7360 h−1. The nano-catalysts could be recovered with a magnet and reused several times (6 times for Suzuki–Miayura reaction) without loss of activity.

AB - Cucurbit[7]uril modified iron oxide nanoparticles (CB[7]NPs) were loaded with palladium to form nano-catalysts (Pd@CB[7]NPs) that, with microwave heating, catalysed Suzuki–Miyaura, Sonogashira, and Mizoroki–Heck cross-coupling reactions. Reactions were run in environmentally benign 1:1 ethanol/water solvent under convenient aerobic conditions. In a preliminary screening, conversions and yields were uniformly high with turn over frequencies (TOF) ranging from 64 to 7360 h−1. The nano-catalysts could be recovered with a magnet and reused several times (6 times for Suzuki–Miayura reaction) without loss of activity.

KW - cross-coupling reactions

KW - cucurbit[7]uril

KW - macrocyclic chemistry

KW - magnetic nano-catalyst

KW - palladium

UR - http://www.scopus.com/inward/record.url?scp=85041081176&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=85041081176&partnerID=8YFLogxK

U2 - 10.1002/chem.201705082

DO - 10.1002/chem.201705082

M3 - Article

C2 - 29297954

AN - SCOPUS:85041081176

VL - 24

SP - 2349

EP - 2353

JO - Chemistry - A European Journal

JF - Chemistry - A European Journal

SN - 0947-6539

IS - 10

ER -

Palladium-Loaded Cucurbit[7]uril-Modified Iron Oxide Nanoparticles for C−C Cross-Coupling Reactions

Abstract

Keywords

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Cite this