Perhaloalkylation of metal enolates-unconventional and versatile

Tynchtyk Amatov; Ullrich Jahn

doi:10.1002/anie.201007672

Perhaloalkylation of metal enolates-unconventional and versatile

Tynchtyk Amatov, Ullrich Jahn

Chemistry

Research output: Contribution to journal › Review article › peer-review

Abstract

Radically unconventional: Natural products with di- and trichloromethyl groups and trifluoromethylated pharmaceuticals and agrochemicials are interesting compounds, often with intriguing properties. These types of compounds can be prepared by the direct perhaloalkylation of carbonyl compounds in which enolate reactivity and radical reactivity are merged (see scheme; Bn=benzyl).

Original language	English (US)
Pages (from-to)	4542-4544
Number of pages	3
Journal	Angewandte Chemie - International Edition
Volume	50
Issue number	20
DOIs	https://doi.org/10.1002/anie.201007672
State	Published - May 9 2011

Keywords

electron transfer
enols
perhaloalkylation
radical reactions
valence tautomerism

ASJC Scopus subject areas

Catalysis
Chemistry(all)

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10.1002/anie.201007672

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abstract = "Radically unconventional: Natural products with di- and trichloromethyl groups and trifluoromethylated pharmaceuticals and agrochemicials are interesting compounds, often with intriguing properties. These types of compounds can be prepared by the direct perhaloalkylation of carbonyl compounds in which enolate reactivity and radical reactivity are merged (see scheme; Bn=benzyl).",

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author = "Tynchtyk Amatov and Ullrich Jahn",

year = "2011",

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doi = "10.1002/anie.201007672",

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AU - Jahn, Ullrich

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N2 - Radically unconventional: Natural products with di- and trichloromethyl groups and trifluoromethylated pharmaceuticals and agrochemicials are interesting compounds, often with intriguing properties. These types of compounds can be prepared by the direct perhaloalkylation of carbonyl compounds in which enolate reactivity and radical reactivity are merged (see scheme; Bn=benzyl).

AB - Radically unconventional: Natural products with di- and trichloromethyl groups and trifluoromethylated pharmaceuticals and agrochemicials are interesting compounds, often with intriguing properties. These types of compounds can be prepared by the direct perhaloalkylation of carbonyl compounds in which enolate reactivity and radical reactivity are merged (see scheme; Bn=benzyl).

KW - electron transfer

KW - enols

KW - perhaloalkylation

KW - radical reactions

KW - valence tautomerism

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M3 - Review article

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Perhaloalkylation of metal enolates-unconventional and versatile

Abstract

Keywords

ASJC Scopus subject areas

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