Phase Behavior of Mixtures of Block Copolymers and a Lithium Salt

Whitney S. Loo, Michael D. Galluzzo, Xiuhong Li, Jacqueline A. Maslyn, Hee Jeung Oh, Katrina I. Mongcopa, Chenhui Zhu, Andrew A. Wang, Xin Wang, Bruce A. Garetz, Nitash P. Balsara

Research output: Contribution to journalArticle

Abstract

We present experimental results on the phase behavior of block copolymer/salt mixtures over a wide range of copolymer compositions, molecular weights, and salt concentrations. The experimental system comprises polystyrene-block-poly(ethylene oxide) and lithium bis(trifluoromethanesulfonyl)imide (LiTFSI) salt. It is well established that LiTFSI interacts favorably with poly(ethylene oxide) relative to polystyrene. The relationship between chain length and copolymer composition at fixed temperature is U-shaped, as seen in experiments on conventional block copolymers and as anticipated from the standard self-consistent field theory (SCFT) of block copolymer melts. The phase behavior can be explained in terms of an effective Flory-Huggins interaction parameter between the polystyrene monomers and poly(ethylene oxide) monomers complexed with the salt, χeff, which increases linearly with salt concentration. The phase behavior of salt-containing block copolymers, plotted on a segregation strength versus copolymer composition plot, is similar to that of conventional (uncharged) block copolymer melts, when the parameter χeff replaces χ in segregation strength.

Original languageEnglish (US)
Pages (from-to)8065-8074
Number of pages10
JournalJournal of Physical Chemistry B
Volume122
Issue number33
DOIs
StatePublished - Aug 23 2018

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Surfaces, Coatings and Films
  • Materials Chemistry

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  • Cite this

    Loo, W. S., Galluzzo, M. D., Li, X., Maslyn, J. A., Oh, H. J., Mongcopa, K. I., Zhu, C., Wang, A. A., Wang, X., Garetz, B. A., & Balsara, N. P. (2018). Phase Behavior of Mixtures of Block Copolymers and a Lithium Salt. Journal of Physical Chemistry B, 122(33), 8065-8074. https://doi.org/10.1021/acs.jpcb.8b04189