@article{fce2d6e6520244d8b9c341dbe5a4e691,
title = "Photochemistry of ortho -Azidocinnamoyl Derivatives: Facile and Modular Synthesis of 2-Acylated Indoles and 2-Substituted Quinolines under Solvent Control",
abstract = "The light-promoted potential of ortho -azidocinnamoyl compounds is evaluated for heterocycle synthesis. Depending on the nature of the solvent, 2-acylated indoles were obtained under aprotic conditions, whereas the use of a protic medium led to 2-substituted quinolines. The synthetic significance of this metal-free method is that, by simply changing the solvent, the reaction outcome can be directed towards different key heterocyclic scaffolds.",
keywords = "azides, indoles, nitrenes, photochemistry, quinolines, rearrangement, solvent effect",
author = "S. Chaabouni and Pinkerton, {N. M.} and S. Abid and C. Galaup and S. Chassaing",
note = "Funding Information: The authors gratefully acknowledge the CNRS and Universit{\'e} Paul Sa-batier-Toulouse III for financial support. This work was supported by the Agence Nationale de Recherche (ANR-13-JS07-0003-01 CiTrON-Fluo) and the CNRS. S.C. thanks the Campus France Agency and the Universit{\'e} de Sfax for financial support, and N.M.P. thanks the Fonda-tion RITC and the Fondation Toulouse Cancer Sant{\'e} for a post-doctoral scholarship.Agence Noaitnael de al Rechecrhe A(NR-13S-J07-0003-01 CTriON-Fulo) Publisher Copyright: {\textcopyright} Georg Thieme Verlag Stuttgart, New York.",
year = "2017",
month = dec,
day = "1",
doi = "10.1055/s-0036-1590861",
language = "English (US)",
volume = "28",
pages = "2614--2618",
journal = "Synlett",
issn = "0936-5214",
publisher = "Georg Thieme Verlag",
number = "19",
}