Photoinduced nickel-catalyzed carbonylation of alkyl halides to acid chlorides

Ajay H. Bansode; Marvin Parasram

doi:10.1016/j.checat.2023.100600

Photoinduced nickel-catalyzed carbonylation of alkyl halides to acid chlorides

Ajay H. Bansode, Marvin Parasram

Chemistry

Research output: Contribution to journal › Comment/debate › peer-review

Abstract

Recently in Angewandte Chemie, Arndtsen and co-workers described a visible-light-mediated carbonylation of alkyl halides to their corresponding acid chlorides using a stable, carbon monoxide (CO)-coordinated Ni(0)/xantphos catalyst. The successful implementation of this CO-coordinated base-metal catalytic system illustrates how challenging carbonylation reactions can be achieved without the use of precious-metal catalysis.

Original language	English (US)
Article number	100600
Journal	Chem Catalysis
Volume	3
Issue number	4
DOIs	https://doi.org/10.1016/j.checat.2023.100600
State	Published - Apr 20 2023

ASJC Scopus subject areas

Chemistry (miscellaneous)
Physical and Theoretical Chemistry
Organic Chemistry

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10.1016/j.checat.2023.100600

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title = "Photoinduced nickel-catalyzed carbonylation of alkyl halides to acid chlorides",

abstract = "Recently in Angewandte Chemie, Arndtsen and co-workers described a visible-light-mediated carbonylation of alkyl halides to their corresponding acid chlorides using a stable, carbon monoxide (CO)-coordinated Ni(0)/xantphos catalyst. The successful implementation of this CO-coordinated base-metal catalytic system illustrates how challenging carbonylation reactions can be achieved without the use of precious-metal catalysis.",

author = "Bansode, {Ajay H.} and Marvin Parasram",

note = "Publisher Copyright: {\textcopyright} 2023",

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AU - Parasram, Marvin

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N2 - Recently in Angewandte Chemie, Arndtsen and co-workers described a visible-light-mediated carbonylation of alkyl halides to their corresponding acid chlorides using a stable, carbon monoxide (CO)-coordinated Ni(0)/xantphos catalyst. The successful implementation of this CO-coordinated base-metal catalytic system illustrates how challenging carbonylation reactions can be achieved without the use of precious-metal catalysis.

AB - Recently in Angewandte Chemie, Arndtsen and co-workers described a visible-light-mediated carbonylation of alkyl halides to their corresponding acid chlorides using a stable, carbon monoxide (CO)-coordinated Ni(0)/xantphos catalyst. The successful implementation of this CO-coordinated base-metal catalytic system illustrates how challenging carbonylation reactions can be achieved without the use of precious-metal catalysis.

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Photoinduced nickel-catalyzed carbonylation of alkyl halides to acid chlorides

Abstract

ASJC Scopus subject areas

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