Photoinduced phase transition of the coordinationally unsaturated d 9 metal centers of bis(N,N-diethylethylenediamine)copper(II) perchlorate within the thermal hysteresis of the spin-exchange interaction

Panče Naumov, Kenji Sakurai, Toru Asaka, Alexei A. Belik, Shin Ichi Adachi, Junichi Takahashi, Shin Ya Koshihara

Research output: Contribution to journalArticlepeer-review

Abstract

Diffraction evidence is presented that the structure of one-dimensional arrays of strained, coordinationally unsaturated d9 pseudo-Jahn-Teller centers of bis(N,N-diethylethylenediamine)copper(II) perchlorate is affected by excitation of the LMCT bands within the hysteresis region of a low-temperature ferromagnetic-to-antiferromagnetic phase transition.

Original languageEnglish (US)
Pages (from-to)1345-1347
Number of pages3
JournalEuropean Journal of Inorganic Chemistry
Issue number7
DOIs
StatePublished - Apr 3 2006

Keywords

  • Jahn-Teller effect
  • Photochromism
  • Photodiffraction
  • Photoinduced phase transitions
  • Thermochromism

ASJC Scopus subject areas

  • Inorganic Chemistry

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