Photoinduced phase transition of the coordinationally unsaturated d 9 metal centers of bis(N,N-diethylethylenediamine)copper(II) perchlorate within the thermal hysteresis of the spin-exchange interaction

Panče Naumov; Kenji Sakurai; Toru Asaka; Alexei A. Belik; Shin Ichi Adachi; Junichi Takahashi; Shin Ya Koshihara

doi:10.1002/ejic.200501058

Photoinduced phase transition of the coordinationally unsaturated d ⁹ metal centers of bis(N,N-diethylethylenediamine)copper(II) perchlorate within the thermal hysteresis of the spin-exchange interaction

Panče Naumov, Kenji Sakurai, Toru Asaka, Alexei A. Belik, Shin Ichi Adachi, Junichi Takahashi, Shin Ya Koshihara

Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

Diffraction evidence is presented that the structure of one-dimensional arrays of strained, coordinationally unsaturated d⁹ pseudo-Jahn-Teller centers of bis(N,N-diethylethylenediamine)copper(II) perchlorate is affected by excitation of the LMCT bands within the hysteresis region of a low-temperature ferromagnetic-to-antiferromagnetic phase transition.

Original language	English (US)
Pages (from-to)	1345-1347
Number of pages	3
Journal	European Journal of Inorganic Chemistry
Issue number	7
DOIs	https://doi.org/10.1002/ejic.200501058
State	Published - Apr 3 2006

Keywords

Jahn-Teller effect
Photochromism
Photodiffraction
Photoinduced phase transitions
Thermochromism

ASJC Scopus subject areas

Inorganic Chemistry

Access to Document

10.1002/ejic.200501058

Cite this

Naumov, P., Sakurai, K., Asaka, T., Belik, A. A., Adachi, S. I., Takahashi, J., & Koshihara, S. Y. (2006). Photoinduced phase transition of the coordinationally unsaturated d ⁹ metal centers of bis(N,N-diethylethylenediamine)copper(II) perchlorate within the thermal hysteresis of the spin-exchange interaction. European Journal of Inorganic Chemistry, (7), 1345-1347. https://doi.org/10.1002/ejic.200501058

Photoinduced phase transition of the coordinationally unsaturated d ⁹ metal centers of bis(N,N-diethylethylenediamine)copper(II) perchlorate within the thermal hysteresis of the spin-exchange interaction. / Naumov, Panče; Sakurai, Kenji; Asaka, Toru et al.
In: European Journal of Inorganic Chemistry, No. 7, 03.04.2006, p. 1345-1347.

Research output: Contribution to journal › Article › peer-review

Naumov, P, Sakurai, K, Asaka, T, Belik, AA, Adachi, SI, Takahashi, J & Koshihara, SY 2006, 'Photoinduced phase transition of the coordinationally unsaturated d ⁹ metal centers of bis(N,N-diethylethylenediamine)copper(II) perchlorate within the thermal hysteresis of the spin-exchange interaction', European Journal of Inorganic Chemistry, no. 7, pp. 1345-1347. https://doi.org/10.1002/ejic.200501058

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abstract = "Diffraction evidence is presented that the structure of one-dimensional arrays of strained, coordinationally unsaturated d9 pseudo-Jahn-Teller centers of bis(N,N-diethylethylenediamine)copper(II) perchlorate is affected by excitation of the LMCT bands within the hysteresis region of a low-temperature ferromagnetic-to-antiferromagnetic phase transition.",

keywords = "Jahn-Teller effect, Photochromism, Photodiffraction, Photoinduced phase transitions, Thermochromism",

author = "Pan{\v c}e Naumov and Kenji Sakurai and Toru Asaka and Belik, {Alexei A.} and Adachi, {Shin Ichi} and Junichi Takahashi and Koshihara, {Shin Ya}",

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T1 - Photoinduced phase transition of the coordinationally unsaturated d 9 metal centers of bis(N,N-diethylethylenediamine)copper(II) perchlorate within the thermal hysteresis of the spin-exchange interaction

AU - Naumov, Panče

AU - Sakurai, Kenji

AU - Asaka, Toru

AU - Belik, Alexei A.

AU - Adachi, Shin Ichi

AU - Takahashi, Junichi

AU - Koshihara, Shin Ya

PY - 2006/4/3

Y1 - 2006/4/3

N2 - Diffraction evidence is presented that the structure of one-dimensional arrays of strained, coordinationally unsaturated d9 pseudo-Jahn-Teller centers of bis(N,N-diethylethylenediamine)copper(II) perchlorate is affected by excitation of the LMCT bands within the hysteresis region of a low-temperature ferromagnetic-to-antiferromagnetic phase transition.

AB - Diffraction evidence is presented that the structure of one-dimensional arrays of strained, coordinationally unsaturated d9 pseudo-Jahn-Teller centers of bis(N,N-diethylethylenediamine)copper(II) perchlorate is affected by excitation of the LMCT bands within the hysteresis region of a low-temperature ferromagnetic-to-antiferromagnetic phase transition.

KW - Jahn-Teller effect

KW - Photochromism

KW - Photodiffraction

KW - Photoinduced phase transitions

KW - Thermochromism

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