Poly(styrene)-supported Alq 3 and BPh 2q

Xian Yong Wang; Marcus Weck

doi:10.1021/ma050579r

Poly(styrene)-supported Alq ₃ and BPh ₂q

Xian Yong Wang, Marcus Weck

Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

We describe the synthesis of 8-hydroxyquinoline-tethered poly(styrene)s as modular precursors for functionalization with metalloquinolates to form either tris(8-hydroxyquinoline)aluminum (Alq ₃) or 8-hydroxyquinoline biphenylboron (BPh ₂q) pendant polymers. All polymers, both in solution and in the solid state, show similar luminescent properties as their corresponding reference compounds Alq ₃ and BPh ₂q while retaining excellent solution-processing properties. These results clearly indicate that the poly(styrene) backbone does not interfere with the photophysical properties of the pendant Alq ₃ and BPh ₂q chromophores but endows solution processability to the materials.

Original language	English (US)
Pages (from-to)	7219-7224
Number of pages	6
Journal	Macromolecules
Volume	38
Issue number	17
DOIs	https://doi.org/10.1021/ma050579r
State	Published - Aug 23 2005

ASJC Scopus subject areas

Organic Chemistry
Polymers and Plastics
Inorganic Chemistry
Materials Chemistry

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10.1021/ma050579r

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title = "Poly(styrene)-supported Alq 3 and BPh 2q",

abstract = "We describe the synthesis of 8-hydroxyquinoline-tethered poly(styrene)s as modular precursors for functionalization with metalloquinolates to form either tris(8-hydroxyquinoline)aluminum (Alq 3) or 8-hydroxyquinoline biphenylboron (BPh 2q) pendant polymers. All polymers, both in solution and in the solid state, show similar luminescent properties as their corresponding reference compounds Alq 3 and BPh 2q while retaining excellent solution-processing properties. These results clearly indicate that the poly(styrene) backbone does not interfere with the photophysical properties of the pendant Alq 3 and BPh 2q chromophores but endows solution processability to the materials.",

author = "Wang, {Xian Yong} and Marcus Weck",

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N2 - We describe the synthesis of 8-hydroxyquinoline-tethered poly(styrene)s as modular precursors for functionalization with metalloquinolates to form either tris(8-hydroxyquinoline)aluminum (Alq 3) or 8-hydroxyquinoline biphenylboron (BPh 2q) pendant polymers. All polymers, both in solution and in the solid state, show similar luminescent properties as their corresponding reference compounds Alq 3 and BPh 2q while retaining excellent solution-processing properties. These results clearly indicate that the poly(styrene) backbone does not interfere with the photophysical properties of the pendant Alq 3 and BPh 2q chromophores but endows solution processability to the materials.

AB - We describe the synthesis of 8-hydroxyquinoline-tethered poly(styrene)s as modular precursors for functionalization with metalloquinolates to form either tris(8-hydroxyquinoline)aluminum (Alq 3) or 8-hydroxyquinoline biphenylboron (BPh 2q) pendant polymers. All polymers, both in solution and in the solid state, show similar luminescent properties as their corresponding reference compounds Alq 3 and BPh 2q while retaining excellent solution-processing properties. These results clearly indicate that the poly(styrene) backbone does not interfere with the photophysical properties of the pendant Alq 3 and BPh 2q chromophores but endows solution processability to the materials.

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Poly(styrene)-supported Alq ₃ and BPh ₂q

Abstract

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