Abstract
Anomalous diffusion of fluids in a restricted geometry which forbids passing of one fluid particle by another has been studied for many years. The detailed dependence of the mobility factor of the single-file diffusion on relevant parameters beyond the strictly one-dimensional limit is not well understood. In this paper, we study the mobility factor of single-file diffusion fluids interacting with a hard potential in two-dimensional pores. We present a rationale for a theory of the dynamic mobility in terms of the equilibrium equation of state, and make preliminary comparison with Monte Carlo simulations of hard discs in a channel.
Original language | English (US) |
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Pages (from-to) | 721-726 |
Number of pages | 6 |
Journal | Molecular Simulation |
Volume | 29 |
Issue number | 12 |
DOIs | |
State | Published - Dec 1 2003 |
Keywords
- Anomalous diffusion
- Equilibrium equation
- Monte Carlo simulations
- Single-file diffusion
ASJC Scopus subject areas
- Chemistry(all)
- Information Systems
- Modeling and Simulation
- Chemical Engineering(all)
- Materials Science(all)
- Condensed Matter Physics