Recognition of imidazoles by strapped zinc(II) porphyrin receptors: Insight into the induced-fit mechanism

Jeremy Brandel; Ali Trabolsi; Frédéric Melin; Mourad Elhabiri; Jean Weiss; Anne Marie Albrecht-Gary

doi:10.1021/ic701590x

Recognition of imidazoles by strapped zinc(II) porphyrin receptors: Insight into the induced-fit mechanism

Jeremy Brandel, Ali Trabolsi, Frédéric Melin, Mourad Elhabiri, Jean Weiss, Anne Marie Albrecht-Gary

Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

Imidazole-porphyrin coordination has become an important tool in the design of self-assembled materials. A combination of spectrophotometric and stopped-flow techniques has been used to gain insight into the control of imidazole binding in the distal pocket of phenanthroline-strapped porphyrins. The binding studies of a variety of imidazole substrates in combination with both hindered and accessible receptors have permitted the determination of the thermodynamic and kinetic parameters associated with the imidazole binding.

Original language	English (US)
Pages (from-to)	9534-9536
Number of pages	3
Journal	Inorganic Chemistry
Volume	46
Issue number	23
DOIs	https://doi.org/10.1021/ic701590x
State	Published - Nov 12 2007

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Inorganic Chemistry

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10.1021/ic701590x

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abstract = "Imidazole-porphyrin coordination has become an important tool in the design of self-assembled materials. A combination of spectrophotometric and stopped-flow techniques has been used to gain insight into the control of imidazole binding in the distal pocket of phenanthroline-strapped porphyrins. The binding studies of a variety of imidazole substrates in combination with both hindered and accessible receptors have permitted the determination of the thermodynamic and kinetic parameters associated with the imidazole binding.",

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AU - Trabolsi, Ali

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AU - Elhabiri, Mourad

AU - Weiss, Jean

AU - Albrecht-Gary, Anne Marie

PY - 2007/11/12

Y1 - 2007/11/12

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AB - Imidazole-porphyrin coordination has become an important tool in the design of self-assembled materials. A combination of spectrophotometric and stopped-flow techniques has been used to gain insight into the control of imidazole binding in the distal pocket of phenanthroline-strapped porphyrins. The binding studies of a variety of imidazole substrates in combination with both hindered and accessible receptors have permitted the determination of the thermodynamic and kinetic parameters associated with the imidazole binding.

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Recognition of imidazoles by strapped zinc(II) porphyrin receptors: Insight into the induced-fit mechanism

Abstract

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