Redox inversion of helicity in propeller-shaped molecules derived from S-methyl cysteine and methioninol

Homar S. Barcena; Andrea E. Holmes; Steffen Zahn; James W. Canary

doi:10.1021/ol0275217

Redox inversion of helicity in propeller-shaped molecules derived from S-methyl cysteine and methioninol

Homar S. Barcena, Andrea E. Holmes, Steffen Zahn, James W. Canary

Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

(Figure presented) One-electron reduction inverts the helicity of copper complexes formed from derivatives of S-methylcysteine and methioninol. The change in conformation of the organic ligand is followed in the exciton-coupled circular dichroism (ECCD) spectra of the complexes.

Original language	English (US)
Pages (from-to)	709-711
Number of pages	3
Journal	Organic Letters
Volume	5
Issue number	5
DOIs	https://doi.org/10.1021/ol0275217
State	Published - Mar 6 2003

ASJC Scopus subject areas

Biochemistry
Physical and Theoretical Chemistry
Organic Chemistry

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10.1021/ol0275217

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@article{71426def08e94a5babc0f7413a15598e,

title = "Redox inversion of helicity in propeller-shaped molecules derived from S-methyl cysteine and methioninol",

abstract = "(Figure presented) One-electron reduction inverts the helicity of copper complexes formed from derivatives of S-methylcysteine and methioninol. The change in conformation of the organic ligand is followed in the exciton-coupled circular dichroism (ECCD) spectra of the complexes.",

author = "Barcena, {Homar S.} and Holmes, {Andrea E.} and Steffen Zahn and Canary, {James W.}",

year = "2003",

month = mar,

day = "6",

doi = "10.1021/ol0275217",

language = "English (US)",

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pages = "709--711",

journal = "Organic Letters",

issn = "1523-7060",

publisher = "American Chemical Society",

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TY - JOUR

T1 - Redox inversion of helicity in propeller-shaped molecules derived from S-methyl cysteine and methioninol

AU - Barcena, Homar S.

AU - Holmes, Andrea E.

AU - Zahn, Steffen

AU - Canary, James W.

PY - 2003/3/6

Y1 - 2003/3/6

N2 - (Figure presented) One-electron reduction inverts the helicity of copper complexes formed from derivatives of S-methylcysteine and methioninol. The change in conformation of the organic ligand is followed in the exciton-coupled circular dichroism (ECCD) spectra of the complexes.

AB - (Figure presented) One-electron reduction inverts the helicity of copper complexes formed from derivatives of S-methylcysteine and methioninol. The change in conformation of the organic ligand is followed in the exciton-coupled circular dichroism (ECCD) spectra of the complexes.

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U2 - 10.1021/ol0275217

DO - 10.1021/ol0275217

M3 - Article

C2 - 12605496

AN - SCOPUS:0037529206

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VL - 5

SP - 709

EP - 711

JO - Organic Letters

JF - Organic Letters

IS - 5

ER -

Redox inversion of helicity in propeller-shaped molecules derived from S-methyl cysteine and methioninol

Abstract

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