Redox-reconfigurable tripodal coordination complexes: Stereodynamic molecular switches

James W. Canary, Shahab Mortezaei, Jian Liang

Research output: Contribution to journalReview articlepeer-review

Abstract

Ligand design principles based on acyclic conformational analysis, dynamic stereochemistry, and hard-soft ligand-metal coordination have led to the development of several redox-triggered chiroptical molecular switches. Factors controlling the helicity of copper(i) and copper(ii) coordination complexes were explored and exploited to create a series of stereodynamic complexes that exhibit remarkable chiroptical properties. In some systems, strong circular dichroic signal could be modulated between on and off states, while in others, it was possible to invert the ellipticity by one-electron oxidation/reduction. These complexes are of inherent interest for their dynamic stereochemical properties, but may also find use in optical display technology, data storage, telecommunications, or electromechanical devices.

Original languageEnglish (US)
Pages (from-to)5850-5860
Number of pages11
JournalChemical Communications
Volume46
Issue number32
DOIs
StatePublished - Aug 28 2010

ASJC Scopus subject areas

  • Catalysis
  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Chemistry(all)
  • Surfaces, Coatings and Films
  • Metals and Alloys
  • Materials Chemistry

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