Shear-induced sphere-to-cylinder transition in diblock copolymer thin films

Young Rae Hong, Douglas H. Adamson, Paul M. Chaikin, Richard A. Register

    Research output: Contribution to journalArticle

    Abstract

    Applying sufficiently strong shear to thin films of a sphere-forming polystyrene-polyisoprene diblock copolymer is shown to induce an order-order transition to cylinders. The transformation is not continuous or epitaxial, as the intercylinder spacing is ca. 10% greater than the spacing between close-packed lines of spheres. The transition is facilitated when the block copolymer has a composition which places it close to the "zero-field" (no shear) sphere/cylinder phase boundary; the shear-induced transformation is more difficult and less effective for a polymer further from this boundary. Applying a modest shear stress to a polymer close to the boundary distorts the hexagonal lattice formed by the spheres without forming cylinders; the mechanical anisotropy produced by this distortion is sufficient to permit a film containing only a single layer of spherical domains to align in shear.

    Original languageEnglish (US)
    Pages (from-to)1687-1691
    Number of pages5
    JournalSoft Matter
    Volume5
    Issue number8
    DOIs
    StatePublished - 2009

    ASJC Scopus subject areas

    • Chemistry(all)
    • Condensed Matter Physics

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  • Cite this

    Hong, Y. R., Adamson, D. H., Chaikin, P. M., & Register, R. A. (2009). Shear-induced sphere-to-cylinder transition in diblock copolymer thin films. Soft Matter, 5(8), 1687-1691. https://doi.org/10.1039/b820312a