Shielded distribution approximation for a wall-bounded classical fluid

J. K. Percus

Research output: Contribution to journalArticlepeer-review

Abstract

We investigate lower order distribution functions in classical fluids in the presence of large-scale inhomogeneities, in particular those imposed by wall contacts. The consequences of the effective shielding of a wall by the nearest particle of the set being considered are determined in the context of two distribution function hierarchies, kinematic and dynamic in origin. The effects of both flat and spherical, hard and soft walls are considered, as well as those of curved and double walls. A few correction sequences to the basic shielding approximation are discussed.

Original languageEnglish (US)
Pages (from-to)657-699
Number of pages43
JournalJournal of Statistical Physics
Volume23
Issue number6
DOIs
StatePublished - Dec 1980

Keywords

  • Classical fluids
  • distribution functions
  • large-scale inhomogeneities
  • shielded distribution approximation
  • wall contacts

ASJC Scopus subject areas

  • Statistical and Nonlinear Physics
  • Mathematical Physics

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