Silica-supported zirconium hydrides as isomerization or hydrogenation catalysts for long-chain olefins

Jeffrey Schwartz; Michael D. Ward

doi:10.1016/0304-5102(80)80085-X

Silica-supported zirconium hydrides as isomerization or hydrogenation catalysts for long-chain olefins

Jeffrey Schwartz, Michael D. Ward

Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

Silica-supported zirconium hydrides exhibit high activity towards olefin isomerization under mild conditions. 1-Butene, 1-hexene, allylbenzene and methylenecyclohexane are each isomerized to their respective thermodynamic mixtures rapidly. Hydrogenation of 1-butene is also observed under H₂, butene are lower than that of isomerization; catalyst lifetime is shorter for hydrogenation than for isomerization of olefins.

Original language	English (US)
Pages (from-to)	465-469
Number of pages	5
Journal	Journal of Molecular Catalysis
Volume	8
Issue number	4
DOIs	https://doi.org/10.1016/0304-5102(80)80085-X
State	Published - Jun 1980

ASJC Scopus subject areas

General Engineering

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title = "Silica-supported zirconium hydrides as isomerization or hydrogenation catalysts for long-chain olefins",

abstract = "Silica-supported zirconium hydrides exhibit high activity towards olefin isomerization under mild conditions. 1-Butene, 1-hexene, allylbenzene and methylenecyclohexane are each isomerized to their respective thermodynamic mixtures rapidly. Hydrogenation of 1-butene is also observed under H2, butene are lower than that of isomerization; catalyst lifetime is shorter for hydrogenation than for isomerization of olefins.",

author = "Jeffrey Schwartz and Ward, {Michael D.}",

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AU - Schwartz, Jeffrey

AU - Ward, Michael D.

PY - 1980/6

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AB - Silica-supported zirconium hydrides exhibit high activity towards olefin isomerization under mild conditions. 1-Butene, 1-hexene, allylbenzene and methylenecyclohexane are each isomerized to their respective thermodynamic mixtures rapidly. Hydrogenation of 1-butene is also observed under H2, butene are lower than that of isomerization; catalyst lifetime is shorter for hydrogenation than for isomerization of olefins.

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Silica-supported zirconium hydrides as isomerization or hydrogenation catalysts for long-chain olefins

Abstract

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