@article{49c05fd0017b47e48be6356d5ffbb904,
title = "Silylene oxonium ylides: di-tert-butylsilylene insertion into C-O bonds",
abstract = "Allylic ethers undergo insertions of silylenes into C-O bonds to form allylic silanes. Silylene insertion into C-O acetal bonds was also observed. Formation of silylene ylide intermediates led to [1,2]-Stevens rearrangement products as well as [2,3]-sigmatropic products depending upon the steric environment of the starting allylic ether.",
keywords = "Allylic silanes, Oxonium ylide, Silylene",
author = "Bourque, {Laura E.} and Haile, {Pamela A.} and Loy, {Janice M.N.} and Woerpel, {K. A.}",
note = "Funding Information: This research was supported by the National Institute of General Medical Sciences of the National Institutes of Health (GM-54909). L.E.B. thanks the Department of Education (GAANN) for a predoctoral fellowship. K.A.W. thanks Amgen and Lilly for awards to support research. We thank Dr. Phil Dennison (UCI) for assistance with NMR spectroscopy and Dr. John Greaves and Ms. Shirin Sorooshian (UCI) for mass spectrometry.",
year = "2009",
month = jul,
day = "11",
doi = "10.1016/j.tet.2009.04.016",
language = "English (US)",
volume = "65",
pages = "5608--5613",
journal = "Tetrahedron",
issn = "0040-4020",
publisher = "Elsevier Limited",
number = "28",
}