Skeletal rearrangements induced by chemical ionization-I. Analogy to solvolysis1 1 NCL Communication No. 2434.

G. Sudhakar Reddy; M. Vairamani; K. G. Das; H. budzikiewicz; Mark M. Green

doi:10.1016/0040-4020(79)87052-0

Skeletal rearrangements induced by chemical ionization-I. Analogy to solvolysis¹ 1 NCL Communication No. 2434.

G. Sudhakar Reddy, M. Vairamani, K. G. Das, H. budzikiewicz, Mark M. Green

Chemical and Biomolecular Engineering

Research output: Contribution to journal › Article › peer-review

Abstract

In contrast to the usual expectation in chemical ionization (CI) mass spectrometry, the CI spectra of a series of aryl 4-nitro-Δ'-cyclohexenes show very low intensity protonated molecular ions while a major share of the ion current is carried by rearrangement ions. The intervention of a rearrangement long known in the solvolysis of cyclohexenyl carbenium ions can account for the observed CI behaviour.

Original language	English (US)
Pages (from-to)	2697-2701
Number of pages	5
Journal	Tetrahedron
Volume	35
Issue number	22
DOIs	https://doi.org/10.1016/0040-4020(79)87052-0
State	Published - 1979

ASJC Scopus subject areas

Biochemistry
Drug Discovery
Organic Chemistry

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title = "Skeletal rearrangements induced by chemical ionization-I. Analogy to solvolysis1 1 NCL Communication No. 2434.",

abstract = "In contrast to the usual expectation in chemical ionization (CI) mass spectrometry, the CI spectra of a series of aryl 4-nitro-Δ'-cyclohexenes show very low intensity protonated molecular ions while a major share of the ion current is carried by rearrangement ions. The intervention of a rearrangement long known in the solvolysis of cyclohexenyl carbenium ions can account for the observed CI behaviour.",

author = "Reddy, {G. Sudhakar} and M. Vairamani and Das, {K. G.} and H. budzikiewicz and Green, {Mark M.}",

year = "1979",

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AU - Reddy, G. Sudhakar

AU - Vairamani, M.

AU - Das, K. G.

AU - budzikiewicz, H.

AU - Green, Mark M.

PY - 1979

Y1 - 1979

N2 - In contrast to the usual expectation in chemical ionization (CI) mass spectrometry, the CI spectra of a series of aryl 4-nitro-Δ'-cyclohexenes show very low intensity protonated molecular ions while a major share of the ion current is carried by rearrangement ions. The intervention of a rearrangement long known in the solvolysis of cyclohexenyl carbenium ions can account for the observed CI behaviour.

AB - In contrast to the usual expectation in chemical ionization (CI) mass spectrometry, the CI spectra of a series of aryl 4-nitro-Δ'-cyclohexenes show very low intensity protonated molecular ions while a major share of the ion current is carried by rearrangement ions. The intervention of a rearrangement long known in the solvolysis of cyclohexenyl carbenium ions can account for the observed CI behaviour.

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ER -

Skeletal rearrangements induced by chemical ionization-I. Analogy to solvolysis¹ 1 NCL Communication No. 2434.

Abstract

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