Abstract
A model classical fluid is constructed by assuming that the direct correlation function c(r - r′) is independent of any applied external field. Thermodynamic consistency requires that c(r - r′) ≥ 0, and permits explicit representation of the model by a many-body interaction potential. In the canonical ensemble, the model shows a phase transition to an infinite density condensed phase, but in the grand canonical ensemble only an anomalous transition to zero density vapor is found to stably exist.
Original language | English (US) |
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Pages (from-to) | 921-930 |
Number of pages | 10 |
Journal | Journal of Statistical Physics |
Volume | 42 |
Issue number | 5-6 |
DOIs | |
State | Published - Mar 1986 |
Keywords
- Nonuniform fluid
- density functional
- many-body forces
- phase transition
ASJC Scopus subject areas
- Statistical and Nonlinear Physics
- Mathematical Physics