Stereoselective synthesis of substituted γ-butyrolactones by the [3 + 2] annulation of allylic silanes with chlorosulfonyl isocyanate: Enantioselective total synthesis of (+)-blastmycinone

Zhi Hui Peng; K. A. Woerpel

doi:10.1021/ol0069960

Stereoselective synthesis of substituted γ-butyrolactones by the [3 + 2] annulation of allylic silanes with chlorosulfonyl isocyanate: Enantioselective total synthesis of (+)-blastmycinone

Zhi Hui Peng, K. A. Woerpel

Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

Equation presented (+)-blastmycinone A stereoselective synthesis of γ-butyrolactones by the [3 + 2] annulation of allylic silanes with N-chlorosulfonyl isocyanate (CSI) was developed. An enantioselective total synthesis of (+)-blastmycinone was accomplished using this annulation as the key step.

Original language	English (US)
Pages (from-to)	675-678
Number of pages	4
Journal	Organic Letters
Volume	3
Issue number	5
DOIs	https://doi.org/10.1021/ol0069960
State	Published - Mar 8 2001

ASJC Scopus subject areas

Biochemistry
Physical and Theoretical Chemistry
Organic Chemistry

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10.1021/ol0069960

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abstract = "Equation presented (+)-blastmycinone A stereoselective synthesis of γ-butyrolactones by the [3 + 2] annulation of allylic silanes with N-chlorosulfonyl isocyanate (CSI) was developed. An enantioselective total synthesis of (+)-blastmycinone was accomplished using this annulation as the key step.",

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AU - Woerpel, K. A.

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N2 - Equation presented (+)-blastmycinone A stereoselective synthesis of γ-butyrolactones by the [3 + 2] annulation of allylic silanes with N-chlorosulfonyl isocyanate (CSI) was developed. An enantioselective total synthesis of (+)-blastmycinone was accomplished using this annulation as the key step.

AB - Equation presented (+)-blastmycinone A stereoselective synthesis of γ-butyrolactones by the [3 + 2] annulation of allylic silanes with N-chlorosulfonyl isocyanate (CSI) was developed. An enantioselective total synthesis of (+)-blastmycinone was accomplished using this annulation as the key step.

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Stereoselective synthesis of substituted γ-butyrolactones by the [3 + 2] annulation of allylic silanes with chlorosulfonyl isocyanate: Enantioselective total synthesis of (+)-blastmycinone

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