Stress tensor of liquid-vapor states of inhomogeneous fluids

Víctor Romero-Rochín, Jerome K. Percus

Research output: Contribution to journalArticlepeer-review

Abstract

The theory of the stress tensor of nonuniform fluids by means of density functional theory is reviewed. We present a general, symmetric, stress tensor valid for any free energy density functional with translational and rotational invariance. We specialize to the nonlocal van der Waals free energy density functional of a simple fluid and study inhomogeneous liquid-vapor coexistence states, separated by either a planar or a spherical interface. It is shown that the stress tensor contains all the information regarding the mechanical equilibrium of the state of the system. On the one hand, it leads to the expected expressions and relationships of the interfacial quantities and, on the other, it allows for a correct separation of the bulk and interfacial contributions to the free energy.

Original languageEnglish (US)
Pages (from-to)5130-5136
Number of pages7
JournalPhysical Review E - Statistical Physics, Plasmas, Fluids, and Related Interdisciplinary Topics
Volume53
Issue number5
DOIs
StatePublished - 1996

ASJC Scopus subject areas

  • Statistical and Nonlinear Physics
  • Statistics and Probability
  • Condensed Matter Physics

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