TY - JOUR
T1 - Structural studies of bis(o-sulfobenzimidato)praseodymium (III) chloride hexahydrate
AU - Icbudak, Hasan
AU - Naumov, Panče
AU - Ristova, Mirjana
AU - Jovanovski, Gligor
N1 - Funding Information:
One of the authors (H.I.) would like to thank the Research Fund of Ondokuz Mayis University for the financial support and encouragement. The financial help from the Ministry of Education and Science of the Republic of Macedonia is gratefully acknowledged.
PY - 2002/3/27
Y1 - 2002/3/27
N2 - A novel rare-earth metal(III) saccharinate, namely bis(o-sulfobenzimidato)praseodymium(III) chloride hexahydrate, is synthesized and its solid-state structure is suggested from the FT IR and UV/vis spectroscopic, thermoanalytical, elemental and magnetic measurements. The OH, CO, SO2 and OD stretchings (the latter isolated in H2O matrix) in the FT mid-infrared spectra of the frozen protiated and partially deuterated analogues of the complex spectra-structural correlations in other saccharinates to predict the structure of the o-sulfobenzimidate residues and the hydration water. The structure features a single crystallographic type of O-coordinated or ionic saccharinato residues, with at least three structural types of water of hydration, and chloride counter-ions in the outer-sphere.
AB - A novel rare-earth metal(III) saccharinate, namely bis(o-sulfobenzimidato)praseodymium(III) chloride hexahydrate, is synthesized and its solid-state structure is suggested from the FT IR and UV/vis spectroscopic, thermoanalytical, elemental and magnetic measurements. The OH, CO, SO2 and OD stretchings (the latter isolated in H2O matrix) in the FT mid-infrared spectra of the frozen protiated and partially deuterated analogues of the complex spectra-structural correlations in other saccharinates to predict the structure of the o-sulfobenzimidate residues and the hydration water. The structure features a single crystallographic type of O-coordinated or ionic saccharinato residues, with at least three structural types of water of hydration, and chloride counter-ions in the outer-sphere.
KW - FT IR
KW - Praseodymium(III) complex
KW - Rare-earth complexes
KW - Saccharinates
KW - Spectroscopy
KW - Thermal analysis
UR - http://www.scopus.com/inward/record.url?scp=0037181397&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=0037181397&partnerID=8YFLogxK
U2 - 10.1016/S0022-2860(01)00815-8
DO - 10.1016/S0022-2860(01)00815-8
M3 - Article
AN - SCOPUS:0037181397
SN - 0022-2860
VL - 606
SP - 77
EP - 86
JO - Journal of Molecular Structure
JF - Journal of Molecular Structure
IS - 1-3
ER -