Structural studies of bis(o-sulfobenzimidato)praseodymium (III) chloride hexahydrate

Hasan Icbudak, Panče Naumov, Mirjana Ristova, Gligor Jovanovski

Research output: Contribution to journalArticle

Abstract

A novel rare-earth metal(III) saccharinate, namely bis(o-sulfobenzimidato)praseodymium(III) chloride hexahydrate, is synthesized and its solid-state structure is suggested from the FT IR and UV/vis spectroscopic, thermoanalytical, elemental and magnetic measurements. The OH, CO, SO2 and OD stretchings (the latter isolated in H2O matrix) in the FT mid-infrared spectra of the frozen protiated and partially deuterated analogues of the complex spectra-structural correlations in other saccharinates to predict the structure of the o-sulfobenzimidate residues and the hydration water. The structure features a single crystallographic type of O-coordinated or ionic saccharinato residues, with at least three structural types of water of hydration, and chloride counter-ions in the outer-sphere.

Original languageEnglish (US)
Pages (from-to)77-86
Number of pages10
JournalJournal of Molecular Structure
Volume606
Issue number1-3
DOIs
StatePublished - Mar 27 2002

Keywords

  • FT IR
  • Praseodymium(III) complex
  • Rare-earth complexes
  • Saccharinates
  • Spectroscopy
  • Thermal analysis

ASJC Scopus subject areas

  • Analytical Chemistry
  • Spectroscopy
  • Organic Chemistry
  • Inorganic Chemistry

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