Studies toward the biomimetic total synthesis of (-)-PF-1018

Robert Webster; Boris Gaspar; Peter Mayer; Dirk Trauner

doi:10.1021/ol400508s

Studies toward the biomimetic total synthesis of (-)-PF-1018

Robert Webster, Boris Gaspar, Peter Mayer, Dirk Trauner

Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

Pericyclic reaction cascades are unparalleled in their ability to quickly generate complex structures with excellent stereocontrol. Herein, the use of a biomimetic Stille/8π electrocyclization/Diels-Alder cascade to successfully assemble the core structure of (-)-PF-1018 is reported.

Original language	English (US)
Pages (from-to)	1866-1869
Number of pages	4
Journal	Organic Letters
Volume	15
Issue number	8
DOIs	https://doi.org/10.1021/ol400508s
State	Published - Apr 19 2013

ASJC Scopus subject areas

Biochemistry
Physical and Theoretical Chemistry
Organic Chemistry

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10.1021/ol400508s

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title = "Studies toward the biomimetic total synthesis of (-)-PF-1018",

abstract = "Pericyclic reaction cascades are unparalleled in their ability to quickly generate complex structures with excellent stereocontrol. Herein, the use of a biomimetic Stille/8π electrocyclization/Diels-Alder cascade to successfully assemble the core structure of (-)-PF-1018 is reported.",

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AU - Mayer, Peter

AU - Trauner, Dirk

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AB - Pericyclic reaction cascades are unparalleled in their ability to quickly generate complex structures with excellent stereocontrol. Herein, the use of a biomimetic Stille/8π electrocyclization/Diels-Alder cascade to successfully assemble the core structure of (-)-PF-1018 is reported.

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Studies toward the biomimetic total synthesis of (-)-PF-1018

Abstract

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