Supramolecular click chemistry with a bisammonium-C60 substrate and a ditopic crown ether host

Uwe Hahn; Mourad Elhabiri; Ali Trabolsi; Haiko Herschbach; Emmanuelle Leize; Alain Van Dorsselaer; Anne Marie Albrecht-Gary; Jean François Nierengarten

doi:10.1002/anie.200501249

Supramolecular click chemistry with a bisammonium-C₆₀ substrate and a ditopic crown ether host

Uwe Hahn, Mourad Elhabiri, Ali Trabolsi, Haiko Herschbach, Emmanuelle Leize, Alain Van Dorsselaer, Anne Marie Albrecht-Gary, Jean François Nierengarten

Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

(Chemical Equation Presented) All clicking into place: Self-complementarity between a bis (crown ether) derivative and a bisammonium fullerene leads to the formation of a stable noncovalent macrocyclic 1:1 complex (see schematic representation). The binding constant for this complex is three orders of magnitude larger than that for other closely related systems as a result of the two-center host-guest topography.

Original language	English (US)
Pages (from-to)	5338-5341
Number of pages	4
Journal	Angewandte Chemie - International Edition
Volume	44
Issue number	33
DOIs	https://doi.org/10.1002/anie.200501249
State	Published - Aug 19 2005

Keywords

Binding studies
Crown compounds
Fullerenes
Host-guest systems
Supramolecular chemistry

ASJC Scopus subject areas

Catalysis
General Chemistry

Access to Document

10.1002/anie.200501249

Cite this

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abstract = "(Chemical Equation Presented) All clicking into place: Self-complementarity between a bis (crown ether) derivative and a bisammonium fullerene leads to the formation of a stable noncovalent macrocyclic 1:1 complex (see schematic representation). The binding constant for this complex is three orders of magnitude larger than that for other closely related systems as a result of the two-center host-guest topography.",

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AU - Trabolsi, Ali

AU - Herschbach, Haiko

AU - Leize, Emmanuelle

AU - Van Dorsselaer, Alain

AU - Albrecht-Gary, Anne Marie

AU - Nierengarten, Jean François

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