Surface initiated living cationic polymerization of 2-oxazolines

Rainer Jordan; Abraham Ulman

doi:10.1021/ja973392r

Surface initiated living cationic polymerization of 2-oxazolines

Rainer Jordan, Abraham Ulman

Chemical and Biomolecular Engineering

Research output: Contribution to journal › Article › peer-review

Abstract

A self-assembled monolayer on a planar gold substrate has been used to initiate the living cationic ring-opening polymerization of 2-ethyl-2-oxazoline. The polymer chain end was functionalized with an alkyl moiety by means of the termination reaction in order to form an amphiphilic brush-type layer. The resulting layer (d ~ 10 nm) of linear poly(N-propionylethylenimine) (PPEI) is of uniform thickness and was found to be very stable.

Original language	English (US)
Pages (from-to)	243-247
Number of pages	5
Journal	Journal of the American Chemical Society
Volume	120
Issue number	2
DOIs	https://doi.org/10.1021/ja973392r
State	Published - Jan 21 1998

ASJC Scopus subject areas

Catalysis
General Chemistry
Biochemistry
Colloid and Surface Chemistry

Access to Document

10.1021/ja973392r

Cite this

@article{d2be16070e6c41a5b4f79064cd4bab5c,

title = "Surface initiated living cationic polymerization of 2-oxazolines",

abstract = "A self-assembled monolayer on a planar gold substrate has been used to initiate the living cationic ring-opening polymerization of 2-ethyl-2-oxazoline. The polymer chain end was functionalized with an alkyl moiety by means of the termination reaction in order to form an amphiphilic brush-type layer. The resulting layer (d ~ 10 nm) of linear poly(N-propionylethylenimine) (PPEI) is of uniform thickness and was found to be very stable.",

author = "Rainer Jordan and Abraham Ulman",

year = "1998",

month = jan,

day = "21",

doi = "10.1021/ja973392r",

language = "English (US)",

volume = "120",

pages = "243--247",

journal = "Journal of the American Chemical Society",

issn = "0002-7863",

publisher = "American Chemical Society",

number = "2",

}

TY - JOUR

T1 - Surface initiated living cationic polymerization of 2-oxazolines

AU - Jordan, Rainer

AU - Ulman, Abraham

PY - 1998/1/21

Y1 - 1998/1/21

N2 - A self-assembled monolayer on a planar gold substrate has been used to initiate the living cationic ring-opening polymerization of 2-ethyl-2-oxazoline. The polymer chain end was functionalized with an alkyl moiety by means of the termination reaction in order to form an amphiphilic brush-type layer. The resulting layer (d ~ 10 nm) of linear poly(N-propionylethylenimine) (PPEI) is of uniform thickness and was found to be very stable.

AB - A self-assembled monolayer on a planar gold substrate has been used to initiate the living cationic ring-opening polymerization of 2-ethyl-2-oxazoline. The polymer chain end was functionalized with an alkyl moiety by means of the termination reaction in order to form an amphiphilic brush-type layer. The resulting layer (d ~ 10 nm) of linear poly(N-propionylethylenimine) (PPEI) is of uniform thickness and was found to be very stable.

UR - http://www.scopus.com/inward/record.url?scp=0032554062&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=0032554062&partnerID=8YFLogxK

U2 - 10.1021/ja973392r

DO - 10.1021/ja973392r

M3 - Article

AN - SCOPUS:0032554062

SN - 0002-7863

VL - 120

SP - 243

EP - 247

JO - Journal of the American Chemical Society

JF - Journal of the American Chemical Society

IS - 2

ER -

Surface initiated living cationic polymerization of 2-oxazolines

Abstract

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Cite this