Synthesis and spectroscopic studies of the nicotinamide adducts of Cobalt(II), Nickel(II) and Zinc(II) chlorides

S. Çakir; E. Biçer; H. Içbudak; P. Naumov; H. Korkmaz; O. Çakir

Synthesis and spectroscopic studies of the nicotinamide adducts of Cobalt(II), Nickel(II) and Zinc(II) chlorides

S. Çakir, E. Biçer, H. Içbudak, P. Naumov, H. Korkmaz, O. Çakir

Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

Nicotinamide (na) adducts of Co(II), Ni(II) and Zn(II) chlorides are synthesized and characterized by thermoanalytical methods (TG, DTG, DTA), FT IR (4000-400 cm^-1) and UV/Vis spectroscopy. Structural similarity is inferred between the octahedral Co and Ni compounds of type [M(na)₂(H₂O)₄]Cl₂. The tetrahedral Zn complex [Zn(na)₂Cl₂] presents a different structure. The coordination of the metal ions in the Co and Ni adducts modelled by semiempirical theoretical methods compares well with the structural data for [Ni(na)₂(H₂O)₄](NO)₂·2H₂O.

Original language	English (US)
Pages (from-to)	371-377
Number of pages	7
Journal	Polish Journal of Chemistry
Volume	75
Issue number	3
State	Published - 2001

Keywords

FT IR
Nicotinamide adducts
Semiempirical calculations
Synthesis
UV/Vis spectra

ASJC Scopus subject areas

General Chemistry

Cite this

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title = "Synthesis and spectroscopic studies of the nicotinamide adducts of Cobalt(II), Nickel(II) and Zinc(II) chlorides",

abstract = "Nicotinamide (na) adducts of Co(II), Ni(II) and Zn(II) chlorides are synthesized and characterized by thermoanalytical methods (TG, DTG, DTA), FT IR (4000-400 cm-1) and UV/Vis spectroscopy. Structural similarity is inferred between the octahedral Co and Ni compounds of type [M(na)2(H2O)4]Cl2. The tetrahedral Zn complex [Zn(na)2Cl2] presents a different structure. The coordination of the metal ions in the Co and Ni adducts modelled by semiempirical theoretical methods compares well with the structural data for [Ni(na)2(H2O)4](NO)2·2H2 O.",

keywords = "FT IR, Nicotinamide adducts, Semiempirical calculations, Synthesis, UV/Vis spectra",

author = "S. {\c C}akir and E. Bi{\c c}er and H. I{\c c}budak and P. Naumov and H. Korkmaz and O. {\c C}akir",

year = "2001",

language = "English (US)",

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journal = "Polish Journal of Chemistry",

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TY - JOUR

T1 - Synthesis and spectroscopic studies of the nicotinamide adducts of Cobalt(II), Nickel(II) and Zinc(II) chlorides

AU - Çakir, S.

AU - Biçer, E.

AU - Içbudak, H.

AU - Naumov, P.

AU - Korkmaz, H.

AU - Çakir, O.

PY - 2001

Y1 - 2001

N2 - Nicotinamide (na) adducts of Co(II), Ni(II) and Zn(II) chlorides are synthesized and characterized by thermoanalytical methods (TG, DTG, DTA), FT IR (4000-400 cm-1) and UV/Vis spectroscopy. Structural similarity is inferred between the octahedral Co and Ni compounds of type [M(na)2(H2O)4]Cl2. The tetrahedral Zn complex [Zn(na)2Cl2] presents a different structure. The coordination of the metal ions in the Co and Ni adducts modelled by semiempirical theoretical methods compares well with the structural data for [Ni(na)2(H2O)4](NO)2·2H2 O.

AB - Nicotinamide (na) adducts of Co(II), Ni(II) and Zn(II) chlorides are synthesized and characterized by thermoanalytical methods (TG, DTG, DTA), FT IR (4000-400 cm-1) and UV/Vis spectroscopy. Structural similarity is inferred between the octahedral Co and Ni compounds of type [M(na)2(H2O)4]Cl2. The tetrahedral Zn complex [Zn(na)2Cl2] presents a different structure. The coordination of the metal ions in the Co and Ni adducts modelled by semiempirical theoretical methods compares well with the structural data for [Ni(na)2(H2O)4](NO)2·2H2 O.

KW - FT IR

KW - Nicotinamide adducts

KW - Semiempirical calculations

KW - Synthesis

KW - UV/Vis spectra

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M3 - Article

AN - SCOPUS:0035529483

SN - 0137-5083

VL - 75

SP - 371

EP - 377

JO - Polish Journal of Chemistry

JF - Polish Journal of Chemistry

IS - 3

ER -

Synthesis and spectroscopic studies of the nicotinamide adducts of Cobalt(II), Nickel(II) and Zinc(II) chlorides

Abstract

Keywords

ASJC Scopus subject areas

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