Synthesis of 1,2-dioxolanes by annulation reactions of peroxycarbenium ions with alkenes

Armando Ramirez; K. A. Woerpel

doi:10.1021/ol051703u

Synthesis of 1,2-dioxolanes by annulation reactions of peroxycarbenium ions with alkenes

Armando Ramirez, K. A. Woerpel

Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

(Chemical Equation Presented) The annulation reactions of alkenes with peroxycarbenium ions enable the synthesis of a variety of functionalizable 1,2-dioxolanes. Triethysilyl-protected peroxycarbenium ions proved to be optimal for the annulation reaction. Using this method, plakinic acid analogues can be synthesized in three steps from the corresponding ketone and alkene.

Original language	English (US)
Pages (from-to)	4617-4620
Number of pages	4
Journal	Organic Letters
Volume	7
Issue number	21
DOIs	https://doi.org/10.1021/ol051703u
State	Published - Oct 13 2005

ASJC Scopus subject areas

Biochemistry
Physical and Theoretical Chemistry
Organic Chemistry

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10.1021/ol051703u

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abstract = "(Chemical Equation Presented) The annulation reactions of alkenes with peroxycarbenium ions enable the synthesis of a variety of functionalizable 1,2-dioxolanes. Triethysilyl-protected peroxycarbenium ions proved to be optimal for the annulation reaction. Using this method, plakinic acid analogues can be synthesized in three steps from the corresponding ketone and alkene.",

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AB - (Chemical Equation Presented) The annulation reactions of alkenes with peroxycarbenium ions enable the synthesis of a variety of functionalizable 1,2-dioxolanes. Triethysilyl-protected peroxycarbenium ions proved to be optimal for the annulation reaction. Using this method, plakinic acid analogues can be synthesized in three steps from the corresponding ketone and alkene.

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Synthesis of 1,2-dioxolanes by annulation reactions of peroxycarbenium ions with alkenes

Abstract

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