The cobalt-catalyzed peroxidation of silyl enol ethers with molecular oxygen and triethylsilane provided silyl monoperoxyketals in 54%-96% yield. These compounds serve as precursors to peroxycarbenium ions, which undergo annulations to provide 1,2-dioxolanes.
|Original language||English (US)|
|Number of pages||4|
|State||Published - Aug 15 2014|
ASJC Scopus subject areas
- Physical and Theoretical Chemistry
- Organic Chemistry