Synthetic studies toward polytwistane hydrocarbon nanorods

Martin Olbrich, Peter Mayer, Dirk Trauner

Research output: Contribution to journalArticle

Abstract

A synthetic strategy toward the intriguing hydrocarbon nanorod polytwistane is outlined. Our approach aims toward the polymerization of acetylene starting from precursors that would provide a helical bias for the formation of polytwistane. Both transition-metal-catalyzed and radical polymerizations were investigated. Two potential initiator molecules were synthesized that could be used for either approach. Although the intended regioselectivities were not observed, unusual organopalladium complexes and numerous compounds with novel carbon skeletons were obtained.

Original languageEnglish (US)
Pages (from-to)2042-2055
Number of pages14
JournalJournal of Organic Chemistry
Volume80
Issue number4
DOIs
StatePublished - Feb 20 2015

ASJC Scopus subject areas

  • Organic Chemistry

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