The crystal structure of copper(II) malonate trihydrate

Panče Naumov; Mirjana Ristova; Bojan Šoptrajanov; Michael G.B. Drew; Seik Weng Ng

The crystal structure of copper(II) malonate trihydrate

Panče Naumov, Mirjana Ristova, Bojan Šoptrajanov, Michael G.B. Drew, Seik Weng Ng

Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

The compound having an empirical formula Cu₈C₂₄H₆₄O₅₆, corresponding to copper(II) malonate trihydrate, is in fact the 2 : 1 co-crystal bis(diaquadimalonatocopper-tetraaquacopper)-[(diaquadimalonatocopper)- bis(tetraaquacopper)](2+) diaquadimalonatocuprate(2-), [(H₂O)₂Cu(O₂CCH₂CO₂) ₂ · Cu(H₂O)₄]₂ · [(H₂O)₂Cu(O₂CCH₂CO₂) ₂ · {Cu-(H₂O)₄}₂]²⁺ [(H₂O)₂Cu(O₂CCH₂CO₂) ₂]^2-. The compound crystallizes in the monoclinic P2₁/c space group, with a = 14.96(2), b = 14.97(2), c = 26.00(3) Å; β = 103.91(1)°; Z = 4, ρ_calc = 2.064 g cm^-3.

Original language	English (US)
Pages (from-to)	701-711
Number of pages	11
Journal	Croatica Chemica Acta
Volume	75
Issue number	3
State	Published - Aug 2002

Keywords

Coordination
Copper
Crystal structure
Hydrogen bonding
Malonate

ASJC Scopus subject areas

General Chemistry

Cite this

@article{9f7d457c54804517864e266145958d07,

title = "The crystal structure of copper(II) malonate trihydrate",

abstract = "The compound having an empirical formula Cu8C24H64O56, corresponding to copper(II) malonate trihydrate, is in fact the 2 : 1 co-crystal bis(diaquadimalonatocopper-tetraaquacopper)-[(diaquadimalonatocopper)- bis(tetraaquacopper)](2+) diaquadimalonatocuprate(2-), [(H2O)2Cu(O2CCH2CO2) 2 · Cu(H2O)4]2 · [(H2O)2Cu(O2CCH2CO2) 2 · {Cu-(H2O)4}2]2+ [(H2O)2Cu(O2CCH2CO2) 2]2-. The compound crystallizes in the monoclinic P21/c space group, with a = 14.96(2), b = 14.97(2), c = 26.00(3) {\AA}; β = 103.91(1)°; Z = 4, ρcalc = 2.064 g cm-3.",

keywords = "Coordination, Copper, Crystal structure, Hydrogen bonding, Malonate",

author = "Pan{\v c}e Naumov and Mirjana Ristova and Bojan {\v S}optrajanov and Drew, {Michael G.B.} and Ng, {Seik Weng}",

year = "2002",

month = aug,

language = "English (US)",

volume = "75",

pages = "701--711",

journal = "Croatica Chemica Acta",

issn = "0011-1643",

publisher = "Croatian Chemical Society",

number = "3",

}

TY - JOUR

T1 - The crystal structure of copper(II) malonate trihydrate

AU - Naumov, Panče

AU - Ristova, Mirjana

AU - Šoptrajanov, Bojan

AU - Drew, Michael G.B.

AU - Ng, Seik Weng

PY - 2002/8

Y1 - 2002/8

N2 - The compound having an empirical formula Cu8C24H64O56, corresponding to copper(II) malonate trihydrate, is in fact the 2 : 1 co-crystal bis(diaquadimalonatocopper-tetraaquacopper)-[(diaquadimalonatocopper)- bis(tetraaquacopper)](2+) diaquadimalonatocuprate(2-), [(H2O)2Cu(O2CCH2CO2) 2 · Cu(H2O)4]2 · [(H2O)2Cu(O2CCH2CO2) 2 · {Cu-(H2O)4}2]2+ [(H2O)2Cu(O2CCH2CO2) 2]2-. The compound crystallizes in the monoclinic P21/c space group, with a = 14.96(2), b = 14.97(2), c = 26.00(3) Å; β = 103.91(1)°; Z = 4, ρcalc = 2.064 g cm-3.

AB - The compound having an empirical formula Cu8C24H64O56, corresponding to copper(II) malonate trihydrate, is in fact the 2 : 1 co-crystal bis(diaquadimalonatocopper-tetraaquacopper)-[(diaquadimalonatocopper)- bis(tetraaquacopper)](2+) diaquadimalonatocuprate(2-), [(H2O)2Cu(O2CCH2CO2) 2 · Cu(H2O)4]2 · [(H2O)2Cu(O2CCH2CO2) 2 · {Cu-(H2O)4}2]2+ [(H2O)2Cu(O2CCH2CO2) 2]2-. The compound crystallizes in the monoclinic P21/c space group, with a = 14.96(2), b = 14.97(2), c = 26.00(3) Å; β = 103.91(1)°; Z = 4, ρcalc = 2.064 g cm-3.

KW - Coordination

KW - Copper

KW - Crystal structure

KW - Hydrogen bonding

KW - Malonate

UR - http://www.scopus.com/inward/record.url?scp=0042308403&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=0042308403&partnerID=8YFLogxK

M3 - Article

AN - SCOPUS:0042308403

SN - 0011-1643

VL - 75

SP - 701

EP - 711

JO - Croatica Chemica Acta

JF - Croatica Chemica Acta

IS - 3

ER -

The crystal structure of copper(II) malonate trihydrate

Abstract

Keywords

ASJC Scopus subject areas

Other files and links

Fingerprint

Cite this